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Bis{N-[5-(4-methoxyphenyl)-1,3,4-oxadiazol-2-yl]ethanimidamidato}copper(II)
The title compound, [Cu(C(11)H(11)N(4)O(2))(2)], was prepared by solvothermal synthesis using 2-amino-5-(4-methoxyphenyl)-1,3,4-oxadiazole and copper sulfate pentahydrate in an acetonitrile solution. The Cu(II) atom lies on an inversion center and is four-coordinated in a slightly distorted squar...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984065/ https://www.ncbi.nlm.nih.gov/pubmed/21580509 http://dx.doi.org/10.1107/S1600536810009050 |
Sumario: | The title compound, [Cu(C(11)H(11)N(4)O(2))(2)], was prepared by solvothermal synthesis using 2-amino-5-(4-methoxyphenyl)-1,3,4-oxadiazole and copper sulfate pentahydrate in an acetonitrile solution. The Cu(II) atom lies on an inversion center and is four-coordinated in a slightly distorted square-planar geometry by four N atoms of the ligands obtained from the formation of a bond between the amine N atom of the oxadiazole molecule and the nitrile C atom of the solvent. In the crystal structure an intermolecular N—H⋯N hydrogen bond links inversion-related molecules. |
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