Bis{N-[5-(4-methoxy­phen­yl)-1,3,4-oxa­diazol-2-yl]ethanimidamidato}copper(II)

The title compound, [Cu(C(11)H(11)N(4)O(2))(2)], was prepared by solvothermal synthesis using 2-amino-5-(4-methoxy­phen­yl)-1,3,4-oxadiazole and copper sulfate penta­hydrate in an acetonitrile solution. The Cu(II) atom lies on an inversion center and is four-coordinated in a slightly distorted squar...

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Detalles Bibliográficos
Autores principales: Djebli, Yacine, Mosbah, Salima, Boufas, Sihem, Bencharif, Leila, Roisnel, Thierry
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984065/
https://www.ncbi.nlm.nih.gov/pubmed/21580509
http://dx.doi.org/10.1107/S1600536810009050
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author Djebli, Yacine
Mosbah, Salima
Boufas, Sihem
Bencharif, Leila
Roisnel, Thierry
author_facet Djebli, Yacine
Mosbah, Salima
Boufas, Sihem
Bencharif, Leila
Roisnel, Thierry
author_sort Djebli, Yacine
collection PubMed
description The title compound, [Cu(C(11)H(11)N(4)O(2))(2)], was prepared by solvothermal synthesis using 2-amino-5-(4-methoxy­phen­yl)-1,3,4-oxadiazole and copper sulfate penta­hydrate in an acetonitrile solution. The Cu(II) atom lies on an inversion center and is four-coordinated in a slightly distorted square-planar geometry by four N atoms of the ligands obtained from the formation of a bond between the amine N atom of the oxadiazole mol­ecule and the nitrile C atom of the solvent. In the crystal structure an inter­molecular N—H⋯N hydrogen bond links inversion-related mol­ecules.
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spelling pubmed-29840652010-12-30 Bis{N-[5-(4-methoxy­phen­yl)-1,3,4-oxa­diazol-2-yl]ethanimidamidato}copper(II) Djebli, Yacine Mosbah, Salima Boufas, Sihem Bencharif, Leila Roisnel, Thierry Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(C(11)H(11)N(4)O(2))(2)], was prepared by solvothermal synthesis using 2-amino-5-(4-methoxy­phen­yl)-1,3,4-oxadiazole and copper sulfate penta­hydrate in an acetonitrile solution. The Cu(II) atom lies on an inversion center and is four-coordinated in a slightly distorted square-planar geometry by four N atoms of the ligands obtained from the formation of a bond between the amine N atom of the oxadiazole mol­ecule and the nitrile C atom of the solvent. In the crystal structure an inter­molecular N—H⋯N hydrogen bond links inversion-related mol­ecules. International Union of Crystallography 2010-03-17 /pmc/articles/PMC2984065/ /pubmed/21580509 http://dx.doi.org/10.1107/S1600536810009050 Text en © Djebli et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Djebli, Yacine
Mosbah, Salima
Boufas, Sihem
Bencharif, Leila
Roisnel, Thierry
Bis{N-[5-(4-methoxy­phen­yl)-1,3,4-oxa­diazol-2-yl]ethanimidamidato}copper(II)
title Bis{N-[5-(4-methoxy­phen­yl)-1,3,4-oxa­diazol-2-yl]ethanimidamidato}copper(II)
title_full Bis{N-[5-(4-methoxy­phen­yl)-1,3,4-oxa­diazol-2-yl]ethanimidamidato}copper(II)
title_fullStr Bis{N-[5-(4-methoxy­phen­yl)-1,3,4-oxa­diazol-2-yl]ethanimidamidato}copper(II)
title_full_unstemmed Bis{N-[5-(4-methoxy­phen­yl)-1,3,4-oxa­diazol-2-yl]ethanimidamidato}copper(II)
title_short Bis{N-[5-(4-methoxy­phen­yl)-1,3,4-oxa­diazol-2-yl]ethanimidamidato}copper(II)
title_sort bis{n-[5-(4-methoxy­phen­yl)-1,3,4-oxa­diazol-2-yl]ethanimidamidato}copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984065/
https://www.ncbi.nlm.nih.gov/pubmed/21580509
http://dx.doi.org/10.1107/S1600536810009050
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AT boufassihem bisn54methoxyphenyl134oxadiazol2ylethanimidamidatocopperii
AT bencharifleila bisn54methoxyphenyl134oxadiazol2ylethanimidamidatocopperii
AT roisnelthierry bisn54methoxyphenyl134oxadiazol2ylethanimidamidatocopperii

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