5,6,7,8-Tetra­hydro­quinoline 1-oxide hemihydrate

In the title compound, C(9)H(11)NO·0.5H(2)O, the asymmetric unit contains two similar mol­ecules of 5,6,7,8-tetra­hydro­quinoline 1-oxide and one water mol­ecule. The water mol­ecule links the two O atoms of both independent N-oxides into dimers via O—H⋯O hydrogen bonds, forming a three-dimensional...

Descripción completa

Detalles Bibliográficos
Autores principales: Karczmarzyk, Zbigniew, Lipińska, Teodozja M., Wysocki, Waldemar, Urbańczyk-Lipkowska, Zofia, Kalicki, Przemysław
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984073/
https://www.ncbi.nlm.nih.gov/pubmed/21580641
http://dx.doi.org/10.1107/S1600536810008779
Descripción
Sumario:In the title compound, C(9)H(11)NO·0.5H(2)O, the asymmetric unit contains two similar mol­ecules of 5,6,7,8-tetra­hydro­quinoline 1-oxide and one water mol­ecule. The water mol­ecule links the two O atoms of both independent N-oxides into dimers via O—H⋯O hydrogen bonds, forming a three-dimensional network along [101], which is additionally stabilized by weak C—H⋯O inter­molecular inter­actions. In each mol­ecule, the saturated six-membered rings exist in a conformation inter­mediate between a half-chair and sofa.

Ejemplares similares