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A trinuclear cobalt–cerium complex: bis­(2,2′-bipyridine)-1κ(2) N,N′;3κ(2) N,N′-hexa-μ-methacrylato-1:2κ(6) O:O′;2:3κ(6) O:O′-nitrato-2κ(2) O,O′-2-cerium(III)-1,3-dicobalt(II)

In the title trinuclear cobalt-cerium complex, [CeCo(2)(C(4)H(5)O(2))(6)(NO(3))(C(10)H(8)N(2))(2)], the Ce(III) and each of the two Co(II) ions are bridged by three bidentate methacrylate ligands. The Ce(III) center is coordinated by six O atoms from six methacrylate ligands and two O atoms from the...

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Autores principales: Wu, Bin, Hou, Tingting
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984076/
https://www.ncbi.nlm.nih.gov/pubmed/21580543
http://dx.doi.org/10.1107/S1600536810010299
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author Wu, Bin
Hou, Tingting
author_facet Wu, Bin
Hou, Tingting
author_sort Wu, Bin
collection PubMed
description In the title trinuclear cobalt-cerium complex, [CeCo(2)(C(4)H(5)O(2))(6)(NO(3))(C(10)H(8)N(2))(2)], the Ce(III) and each of the two Co(II) ions are bridged by three bidentate methacrylate ligands. The Ce(III) center is coordinated by six O atoms from six methacrylate ligands and two O atoms from the nitrate anion in a distorted square-anti­prismatic geometry. Each Co(II) ion is coordinated by three O atoms from three methacrylate ligands and two N atoms from a 2,2′-bipyridine ligand in a distorted trigonal-pyramidal geometry. In the crystal structure, π–π inter­actions between the aromatic rings [centroid–centroid distances of 3.816 (8) and 3.756 (8) Å] link the mol­ecules into chains propagated in [01[Image: see text]]. Weak inter­molecular C—H⋯O hydrogen bonds further stabilize the crystal packing.
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spelling pubmed-29840762010-12-30 A trinuclear cobalt–cerium complex: bis­(2,2′-bipyridine)-1κ(2) N,N′;3κ(2) N,N′-hexa-μ-methacrylato-1:2κ(6) O:O′;2:3κ(6) O:O′-nitrato-2κ(2) O,O′-2-cerium(III)-1,3-dicobalt(II) Wu, Bin Hou, Tingting Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title trinuclear cobalt-cerium complex, [CeCo(2)(C(4)H(5)O(2))(6)(NO(3))(C(10)H(8)N(2))(2)], the Ce(III) and each of the two Co(II) ions are bridged by three bidentate methacrylate ligands. The Ce(III) center is coordinated by six O atoms from six methacrylate ligands and two O atoms from the nitrate anion in a distorted square-anti­prismatic geometry. Each Co(II) ion is coordinated by three O atoms from three methacrylate ligands and two N atoms from a 2,2′-bipyridine ligand in a distorted trigonal-pyramidal geometry. In the crystal structure, π–π inter­actions between the aromatic rings [centroid–centroid distances of 3.816 (8) and 3.756 (8) Å] link the mol­ecules into chains propagated in [01[Image: see text]]. Weak inter­molecular C—H⋯O hydrogen bonds further stabilize the crystal packing. International Union of Crystallography 2010-03-27 /pmc/articles/PMC2984076/ /pubmed/21580543 http://dx.doi.org/10.1107/S1600536810010299 Text en © Wu and Hou 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wu, Bin
Hou, Tingting
A trinuclear cobalt–cerium complex: bis­(2,2′-bipyridine)-1κ(2) N,N′;3κ(2) N,N′-hexa-μ-methacrylato-1:2κ(6) O:O′;2:3κ(6) O:O′-nitrato-2κ(2) O,O′-2-cerium(III)-1,3-dicobalt(II)
title A trinuclear cobalt–cerium complex: bis­(2,2′-bipyridine)-1κ(2) N,N′;3κ(2) N,N′-hexa-μ-methacrylato-1:2κ(6) O:O′;2:3κ(6) O:O′-nitrato-2κ(2) O,O′-2-cerium(III)-1,3-dicobalt(II)
title_full A trinuclear cobalt–cerium complex: bis­(2,2′-bipyridine)-1κ(2) N,N′;3κ(2) N,N′-hexa-μ-methacrylato-1:2κ(6) O:O′;2:3κ(6) O:O′-nitrato-2κ(2) O,O′-2-cerium(III)-1,3-dicobalt(II)
title_fullStr A trinuclear cobalt–cerium complex: bis­(2,2′-bipyridine)-1κ(2) N,N′;3κ(2) N,N′-hexa-μ-methacrylato-1:2κ(6) O:O′;2:3κ(6) O:O′-nitrato-2κ(2) O,O′-2-cerium(III)-1,3-dicobalt(II)
title_full_unstemmed A trinuclear cobalt–cerium complex: bis­(2,2′-bipyridine)-1κ(2) N,N′;3κ(2) N,N′-hexa-μ-methacrylato-1:2κ(6) O:O′;2:3κ(6) O:O′-nitrato-2κ(2) O,O′-2-cerium(III)-1,3-dicobalt(II)
title_short A trinuclear cobalt–cerium complex: bis­(2,2′-bipyridine)-1κ(2) N,N′;3κ(2) N,N′-hexa-μ-methacrylato-1:2κ(6) O:O′;2:3κ(6) O:O′-nitrato-2κ(2) O,O′-2-cerium(III)-1,3-dicobalt(II)
title_sort trinuclear cobalt–cerium complex: bis­(2,2′-bipyridine)-1κ(2) n,n′;3κ(2) n,n′-hexa-μ-methacrylato-1:2κ(6) o:o′;2:3κ(6) o:o′-nitrato-2κ(2) o,o′-2-cerium(iii)-1,3-dicobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984076/
https://www.ncbi.nlm.nih.gov/pubmed/21580543
http://dx.doi.org/10.1107/S1600536810010299
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