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A trinuclear cobalt–cerium complex: bis(2,2′-bipyridine)-1κ(2) N,N′;3κ(2) N,N′-hexa-μ-methacrylato-1:2κ(6) O:O′;2:3κ(6) O:O′-nitrato-2κ(2) O,O′-2-cerium(III)-1,3-dicobalt(II)
In the title trinuclear cobalt-cerium complex, [CeCo(2)(C(4)H(5)O(2))(6)(NO(3))(C(10)H(8)N(2))(2)], the Ce(III) and each of the two Co(II) ions are bridged by three bidentate methacrylate ligands. The Ce(III) center is coordinated by six O atoms from six methacrylate ligands and two O atoms from the...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984076/ https://www.ncbi.nlm.nih.gov/pubmed/21580543 http://dx.doi.org/10.1107/S1600536810010299 |
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author | Wu, Bin Hou, Tingting |
author_facet | Wu, Bin Hou, Tingting |
author_sort | Wu, Bin |
collection | PubMed |
description | In the title trinuclear cobalt-cerium complex, [CeCo(2)(C(4)H(5)O(2))(6)(NO(3))(C(10)H(8)N(2))(2)], the Ce(III) and each of the two Co(II) ions are bridged by three bidentate methacrylate ligands. The Ce(III) center is coordinated by six O atoms from six methacrylate ligands and two O atoms from the nitrate anion in a distorted square-antiprismatic geometry. Each Co(II) ion is coordinated by three O atoms from three methacrylate ligands and two N atoms from a 2,2′-bipyridine ligand in a distorted trigonal-pyramidal geometry. In the crystal structure, π–π interactions between the aromatic rings [centroid–centroid distances of 3.816 (8) and 3.756 (8) Å] link the molecules into chains propagated in [01[Image: see text]]. Weak intermolecular C—H⋯O hydrogen bonds further stabilize the crystal packing. |
format | Text |
id | pubmed-2984076 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29840762010-12-30 A trinuclear cobalt–cerium complex: bis(2,2′-bipyridine)-1κ(2) N,N′;3κ(2) N,N′-hexa-μ-methacrylato-1:2κ(6) O:O′;2:3κ(6) O:O′-nitrato-2κ(2) O,O′-2-cerium(III)-1,3-dicobalt(II) Wu, Bin Hou, Tingting Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title trinuclear cobalt-cerium complex, [CeCo(2)(C(4)H(5)O(2))(6)(NO(3))(C(10)H(8)N(2))(2)], the Ce(III) and each of the two Co(II) ions are bridged by three bidentate methacrylate ligands. The Ce(III) center is coordinated by six O atoms from six methacrylate ligands and two O atoms from the nitrate anion in a distorted square-antiprismatic geometry. Each Co(II) ion is coordinated by three O atoms from three methacrylate ligands and two N atoms from a 2,2′-bipyridine ligand in a distorted trigonal-pyramidal geometry. In the crystal structure, π–π interactions between the aromatic rings [centroid–centroid distances of 3.816 (8) and 3.756 (8) Å] link the molecules into chains propagated in [01[Image: see text]]. Weak intermolecular C—H⋯O hydrogen bonds further stabilize the crystal packing. International Union of Crystallography 2010-03-27 /pmc/articles/PMC2984076/ /pubmed/21580543 http://dx.doi.org/10.1107/S1600536810010299 Text en © Wu and Hou 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wu, Bin Hou, Tingting A trinuclear cobalt–cerium complex: bis(2,2′-bipyridine)-1κ(2) N,N′;3κ(2) N,N′-hexa-μ-methacrylato-1:2κ(6) O:O′;2:3κ(6) O:O′-nitrato-2κ(2) O,O′-2-cerium(III)-1,3-dicobalt(II) |
title | A trinuclear cobalt–cerium complex: bis(2,2′-bipyridine)-1κ(2)
N,N′;3κ(2)
N,N′-hexa-μ-methacrylato-1:2κ(6)
O:O′;2:3κ(6)
O:O′-nitrato-2κ(2)
O,O′-2-cerium(III)-1,3-dicobalt(II) |
title_full | A trinuclear cobalt–cerium complex: bis(2,2′-bipyridine)-1κ(2)
N,N′;3κ(2)
N,N′-hexa-μ-methacrylato-1:2κ(6)
O:O′;2:3κ(6)
O:O′-nitrato-2κ(2)
O,O′-2-cerium(III)-1,3-dicobalt(II) |
title_fullStr | A trinuclear cobalt–cerium complex: bis(2,2′-bipyridine)-1κ(2)
N,N′;3κ(2)
N,N′-hexa-μ-methacrylato-1:2κ(6)
O:O′;2:3κ(6)
O:O′-nitrato-2κ(2)
O,O′-2-cerium(III)-1,3-dicobalt(II) |
title_full_unstemmed | A trinuclear cobalt–cerium complex: bis(2,2′-bipyridine)-1κ(2)
N,N′;3κ(2)
N,N′-hexa-μ-methacrylato-1:2κ(6)
O:O′;2:3κ(6)
O:O′-nitrato-2κ(2)
O,O′-2-cerium(III)-1,3-dicobalt(II) |
title_short | A trinuclear cobalt–cerium complex: bis(2,2′-bipyridine)-1κ(2)
N,N′;3κ(2)
N,N′-hexa-μ-methacrylato-1:2κ(6)
O:O′;2:3κ(6)
O:O′-nitrato-2κ(2)
O,O′-2-cerium(III)-1,3-dicobalt(II) |
title_sort | trinuclear cobalt–cerium complex: bis(2,2′-bipyridine)-1κ(2)
n,n′;3κ(2)
n,n′-hexa-μ-methacrylato-1:2κ(6)
o:o′;2:3κ(6)
o:o′-nitrato-2κ(2)
o,o′-2-cerium(iii)-1,3-dicobalt(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984076/ https://www.ncbi.nlm.nih.gov/pubmed/21580543 http://dx.doi.org/10.1107/S1600536810010299 |
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