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Bis(isopropyl­triphenyl­phospho­nium) di-μ-iodido-bis­[iodidocopper(I)]

The title compound, (C(21)H(22)P)(2)[Cu(2)I(4)], prepared from reaction between copper powder, iodine and isopropyl triphenyl­phospho­nium iodide in hydroxy­acetone (acetol), shows an already known Cu(2)I(4) (2−) anion with a planar conformation [Cu—I range = 2.5108 (3)–2.5844 (3) Å and I—Cu—I range...

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Detalles Bibliográficos
Autores principales: Jalilian, Ehsan, Lidin, Sven
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984081/
https://www.ncbi.nlm.nih.gov/pubmed/21580528
http://dx.doi.org/10.1107/S1600536810010196
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author Jalilian, Ehsan
Lidin, Sven
author_facet Jalilian, Ehsan
Lidin, Sven
author_sort Jalilian, Ehsan
collection PubMed
description The title compound, (C(21)H(22)P)(2)[Cu(2)I(4)], prepared from reaction between copper powder, iodine and isopropyl triphenyl­phospho­nium iodide in hydroxy­acetone (acetol), shows an already known Cu(2)I(4) (2−) anion with a planar conformation [Cu—I range = 2.5108 (3)–2.5844 (3) Å and I—Cu—I range = 110.821 (10)–125.401 (10)°].
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spelling pubmed-29840812010-12-30 Bis(isopropyl­triphenyl­phospho­nium) di-μ-iodido-bis­[iodidocopper(I)] Jalilian, Ehsan Lidin, Sven Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(21)H(22)P)(2)[Cu(2)I(4)], prepared from reaction between copper powder, iodine and isopropyl triphenyl­phospho­nium iodide in hydroxy­acetone (acetol), shows an already known Cu(2)I(4) (2−) anion with a planar conformation [Cu—I range = 2.5108 (3)–2.5844 (3) Å and I—Cu—I range = 110.821 (10)–125.401 (10)°]. International Union of Crystallography 2010-03-24 /pmc/articles/PMC2984081/ /pubmed/21580528 http://dx.doi.org/10.1107/S1600536810010196 Text en © Jalilian and Lidin 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jalilian, Ehsan
Lidin, Sven
Bis(isopropyl­triphenyl­phospho­nium) di-μ-iodido-bis­[iodidocopper(I)]
title Bis(isopropyl­triphenyl­phospho­nium) di-μ-iodido-bis­[iodidocopper(I)]
title_full Bis(isopropyl­triphenyl­phospho­nium) di-μ-iodido-bis­[iodidocopper(I)]
title_fullStr Bis(isopropyl­triphenyl­phospho­nium) di-μ-iodido-bis­[iodidocopper(I)]
title_full_unstemmed Bis(isopropyl­triphenyl­phospho­nium) di-μ-iodido-bis­[iodidocopper(I)]
title_short Bis(isopropyl­triphenyl­phospho­nium) di-μ-iodido-bis­[iodidocopper(I)]
title_sort bis(isopropyl­triphenyl­phospho­nium) di-μ-iodido-bis­[iodidocopper(i)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984081/
https://www.ncbi.nlm.nih.gov/pubmed/21580528
http://dx.doi.org/10.1107/S1600536810010196
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