catena-Poly[copper(II)-bis­(μ-3-cyano-2-hydroxy­propionato)-κ(3) N:O (1),O (2);κ(3) O (1),O (2):N-copper(II)]

The title compound, [Cu(C(4)H(4)NO(3))(2)](n), exhibits a double-chain structure extending along [100]. The Cu(II) atom, lying on an inversion center, is coordinated by two cyano N atoms from two 3-cyano-2-hydroxy­propionate ligands and two hydr­oxy O atoms and two carboxyl­ate O atom from two other...

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Detalles Bibliográficos
Autores principales: Wang, Ji-Dong, Han, Shu-Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984082/
https://www.ncbi.nlm.nih.gov/pubmed/21580472
http://dx.doi.org/10.1107/S1600536810007129
Descripción
Sumario:The title compound, [Cu(C(4)H(4)NO(3))(2)](n), exhibits a double-chain structure extending along [100]. The Cu(II) atom, lying on an inversion center, is coordinated by two cyano N atoms from two 3-cyano-2-hydroxy­propionate ligands and two hydr­oxy O atoms and two carboxyl­ate O atom from two other two ligands in a distorted octa­hedral geometry. Inter­molecular C—H⋯O and O—H⋯O hydrogen bonds connect the chains into a three-dimensional structure.

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