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catena-Poly[copper(II)-bis­(μ-3-cyano-2-hydroxy­propionato)-κ(3) N:O (1),O (2);κ(3) O (1),O (2):N-copper(II)]

The title compound, [Cu(C(4)H(4)NO(3))(2)](n), exhibits a double-chain structure extending along [100]. The Cu(II) atom, lying on an inversion center, is coordinated by two cyano N atoms from two 3-cyano-2-hydroxy­propionate ligands and two hydr­oxy O atoms and two carboxyl­ate O atom from two other...

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Detalles Bibliográficos
Autores principales: Wang, Ji-Dong, Han, Shu-Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984082/
https://www.ncbi.nlm.nih.gov/pubmed/21580472
http://dx.doi.org/10.1107/S1600536810007129
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author Wang, Ji-Dong
Han, Shu-Min
author_facet Wang, Ji-Dong
Han, Shu-Min
author_sort Wang, Ji-Dong
collection PubMed
description The title compound, [Cu(C(4)H(4)NO(3))(2)](n), exhibits a double-chain structure extending along [100]. The Cu(II) atom, lying on an inversion center, is coordinated by two cyano N atoms from two 3-cyano-2-hydroxy­propionate ligands and two hydr­oxy O atoms and two carboxyl­ate O atom from two other two ligands in a distorted octa­hedral geometry. Inter­molecular C—H⋯O and O—H⋯O hydrogen bonds connect the chains into a three-dimensional structure.
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spelling pubmed-29840822010-12-30 catena-Poly[copper(II)-bis­(μ-3-cyano-2-hydroxy­propionato)-κ(3) N:O (1),O (2);κ(3) O (1),O (2):N-copper(II)] Wang, Ji-Dong Han, Shu-Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(C(4)H(4)NO(3))(2)](n), exhibits a double-chain structure extending along [100]. The Cu(II) atom, lying on an inversion center, is coordinated by two cyano N atoms from two 3-cyano-2-hydroxy­propionate ligands and two hydr­oxy O atoms and two carboxyl­ate O atom from two other two ligands in a distorted octa­hedral geometry. Inter­molecular C—H⋯O and O—H⋯O hydrogen bonds connect the chains into a three-dimensional structure. International Union of Crystallography 2010-03-03 /pmc/articles/PMC2984082/ /pubmed/21580472 http://dx.doi.org/10.1107/S1600536810007129 Text en © Wang and Han 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Ji-Dong
Han, Shu-Min
catena-Poly[copper(II)-bis­(μ-3-cyano-2-hydroxy­propionato)-κ(3) N:O (1),O (2);κ(3) O (1),O (2):N-copper(II)]
title catena-Poly[copper(II)-bis­(μ-3-cyano-2-hydroxy­propionato)-κ(3) N:O (1),O (2);κ(3) O (1),O (2):N-copper(II)]
title_full catena-Poly[copper(II)-bis­(μ-3-cyano-2-hydroxy­propionato)-κ(3) N:O (1),O (2);κ(3) O (1),O (2):N-copper(II)]
title_fullStr catena-Poly[copper(II)-bis­(μ-3-cyano-2-hydroxy­propionato)-κ(3) N:O (1),O (2);κ(3) O (1),O (2):N-copper(II)]
title_full_unstemmed catena-Poly[copper(II)-bis­(μ-3-cyano-2-hydroxy­propionato)-κ(3) N:O (1),O (2);κ(3) O (1),O (2):N-copper(II)]
title_short catena-Poly[copper(II)-bis­(μ-3-cyano-2-hydroxy­propionato)-κ(3) N:O (1),O (2);κ(3) O (1),O (2):N-copper(II)]
title_sort catena-poly[copper(ii)-bis­(μ-3-cyano-2-hydroxy­propionato)-κ(3) n:o (1),o (2);κ(3) o (1),o (2):n-copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984082/
https://www.ncbi.nlm.nih.gov/pubmed/21580472
http://dx.doi.org/10.1107/S1600536810007129
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