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catena-Poly[copper(II)-bis(μ-3-cyano-2-hydroxypropionato)-κ(3) N:O (1),O (2);κ(3) O (1),O (2):N-copper(II)]
The title compound, [Cu(C(4)H(4)NO(3))(2)](n), exhibits a double-chain structure extending along [100]. The Cu(II) atom, lying on an inversion center, is coordinated by two cyano N atoms from two 3-cyano-2-hydroxypropionate ligands and two hydroxy O atoms and two carboxylate O atom from two other...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984082/ https://www.ncbi.nlm.nih.gov/pubmed/21580472 http://dx.doi.org/10.1107/S1600536810007129 |
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author | Wang, Ji-Dong Han, Shu-Min |
author_facet | Wang, Ji-Dong Han, Shu-Min |
author_sort | Wang, Ji-Dong |
collection | PubMed |
description | The title compound, [Cu(C(4)H(4)NO(3))(2)](n), exhibits a double-chain structure extending along [100]. The Cu(II) atom, lying on an inversion center, is coordinated by two cyano N atoms from two 3-cyano-2-hydroxypropionate ligands and two hydroxy O atoms and two carboxylate O atom from two other two ligands in a distorted octahedral geometry. Intermolecular C—H⋯O and O—H⋯O hydrogen bonds connect the chains into a three-dimensional structure. |
format | Text |
id | pubmed-2984082 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29840822010-12-30 catena-Poly[copper(II)-bis(μ-3-cyano-2-hydroxypropionato)-κ(3) N:O (1),O (2);κ(3) O (1),O (2):N-copper(II)] Wang, Ji-Dong Han, Shu-Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(C(4)H(4)NO(3))(2)](n), exhibits a double-chain structure extending along [100]. The Cu(II) atom, lying on an inversion center, is coordinated by two cyano N atoms from two 3-cyano-2-hydroxypropionate ligands and two hydroxy O atoms and two carboxylate O atom from two other two ligands in a distorted octahedral geometry. Intermolecular C—H⋯O and O—H⋯O hydrogen bonds connect the chains into a three-dimensional structure. International Union of Crystallography 2010-03-03 /pmc/articles/PMC2984082/ /pubmed/21580472 http://dx.doi.org/10.1107/S1600536810007129 Text en © Wang and Han 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Ji-Dong Han, Shu-Min catena-Poly[copper(II)-bis(μ-3-cyano-2-hydroxypropionato)-κ(3) N:O (1),O (2);κ(3) O (1),O (2):N-copper(II)] |
title |
catena-Poly[copper(II)-bis(μ-3-cyano-2-hydroxypropionato)-κ(3)
N:O
(1),O
(2);κ(3)
O
(1),O
(2):N-copper(II)] |
title_full |
catena-Poly[copper(II)-bis(μ-3-cyano-2-hydroxypropionato)-κ(3)
N:O
(1),O
(2);κ(3)
O
(1),O
(2):N-copper(II)] |
title_fullStr |
catena-Poly[copper(II)-bis(μ-3-cyano-2-hydroxypropionato)-κ(3)
N:O
(1),O
(2);κ(3)
O
(1),O
(2):N-copper(II)] |
title_full_unstemmed |
catena-Poly[copper(II)-bis(μ-3-cyano-2-hydroxypropionato)-κ(3)
N:O
(1),O
(2);κ(3)
O
(1),O
(2):N-copper(II)] |
title_short |
catena-Poly[copper(II)-bis(μ-3-cyano-2-hydroxypropionato)-κ(3)
N:O
(1),O
(2);κ(3)
O
(1),O
(2):N-copper(II)] |
title_sort | catena-poly[copper(ii)-bis(μ-3-cyano-2-hydroxypropionato)-κ(3)
n:o
(1),o
(2);κ(3)
o
(1),o
(2):n-copper(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984082/ https://www.ncbi.nlm.nih.gov/pubmed/21580472 http://dx.doi.org/10.1107/S1600536810007129 |
work_keys_str_mv | AT wangjidong catenapolycopperiibism3cyano2hydroxypropionatok3no1o2k3o1o2ncopperii AT hanshumin catenapolycopperiibism3cyano2hydroxypropionatok3no1o2k3o1o2ncopperii |