catena-Poly[[aqua­cadmium(II)]-bis­(μ(2)-4-chloro­benzoato)]

In the title complex, [Cd(C(7)H(4)ClO(2))(2)(H(2)O)](n), the Cd atom lies on a twofold axis and adopts a square-pyramidal coordination geometry. The water mol­ecule occupies the axial site with O atoms from four different 4-chloro­benzoato ligands in the equatorial plane. Pairs of 4-chloro­benzoato...

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Detalles Bibliográficos
Autores principales: Wan, Chong-Qing, Wang, Zi-Jia, Zhang, Fan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984089/
https://www.ncbi.nlm.nih.gov/pubmed/21580493
http://dx.doi.org/10.1107/S1600536810008068
Descripción
Sumario:In the title complex, [Cd(C(7)H(4)ClO(2))(2)(H(2)O)](n), the Cd atom lies on a twofold axis and adopts a square-pyramidal coordination geometry. The water mol­ecule occupies the axial site with O atoms from four different 4-chloro­benzoato ligands in the equatorial plane. Pairs of 4-chloro­benzoato ligands bridge adjacent Cd(II) ions, generating an infinite chain structure along the c axis. Parallel polymeric chains are further inter­connected through water–acetate O—H⋯O hydrogen bonds, forming layers in the bc plane.

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