catena-Poly[[aqua­cadmium(II)]-bis­(μ(2)-4-chloro­benzoato)]

In the title complex, [Cd(C(7)H(4)ClO(2))(2)(H(2)O)](n), the Cd atom lies on a twofold axis and adopts a square-pyramidal coordination geometry. The water mol­ecule occupies the axial site with O atoms from four different 4-chloro­benzoato ligands in the equatorial plane. Pairs of 4-chloro­benzoato...

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Detalles Bibliográficos
Autores principales: Wan, Chong-Qing, Wang, Zi-Jia, Zhang, Fan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984089/
https://www.ncbi.nlm.nih.gov/pubmed/21580493
http://dx.doi.org/10.1107/S1600536810008068
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author Wan, Chong-Qing
Wang, Zi-Jia
Zhang, Fan
author_facet Wan, Chong-Qing
Wang, Zi-Jia
Zhang, Fan
author_sort Wan, Chong-Qing
collection PubMed
description In the title complex, [Cd(C(7)H(4)ClO(2))(2)(H(2)O)](n), the Cd atom lies on a twofold axis and adopts a square-pyramidal coordination geometry. The water mol­ecule occupies the axial site with O atoms from four different 4-chloro­benzoato ligands in the equatorial plane. Pairs of 4-chloro­benzoato ligands bridge adjacent Cd(II) ions, generating an infinite chain structure along the c axis. Parallel polymeric chains are further inter­connected through water–acetate O—H⋯O hydrogen bonds, forming layers in the bc plane.
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spelling pubmed-29840892010-12-30 catena-Poly[[aqua­cadmium(II)]-bis­(μ(2)-4-chloro­benzoato)] Wan, Chong-Qing Wang, Zi-Jia Zhang, Fan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cd(C(7)H(4)ClO(2))(2)(H(2)O)](n), the Cd atom lies on a twofold axis and adopts a square-pyramidal coordination geometry. The water mol­ecule occupies the axial site with O atoms from four different 4-chloro­benzoato ligands in the equatorial plane. Pairs of 4-chloro­benzoato ligands bridge adjacent Cd(II) ions, generating an infinite chain structure along the c axis. Parallel polymeric chains are further inter­connected through water–acetate O—H⋯O hydrogen bonds, forming layers in the bc plane. International Union of Crystallography 2010-03-06 /pmc/articles/PMC2984089/ /pubmed/21580493 http://dx.doi.org/10.1107/S1600536810008068 Text en © Wan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wan, Chong-Qing
Wang, Zi-Jia
Zhang, Fan
catena-Poly[[aqua­cadmium(II)]-bis­(μ(2)-4-chloro­benzoato)]
title catena-Poly[[aqua­cadmium(II)]-bis­(μ(2)-4-chloro­benzoato)]
title_full catena-Poly[[aqua­cadmium(II)]-bis­(μ(2)-4-chloro­benzoato)]
title_fullStr catena-Poly[[aqua­cadmium(II)]-bis­(μ(2)-4-chloro­benzoato)]
title_full_unstemmed catena-Poly[[aqua­cadmium(II)]-bis­(μ(2)-4-chloro­benzoato)]
title_short catena-Poly[[aqua­cadmium(II)]-bis­(μ(2)-4-chloro­benzoato)]
title_sort catena-poly[[aqua­cadmium(ii)]-bis­(μ(2)-4-chloro­benzoato)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2984089/
https://www.ncbi.nlm.nih.gov/pubmed/21580493
http://dx.doi.org/10.1107/S1600536810008068
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