Flexible Two-Dimensional Square-Grid Coordination Polymers: Structures and Functions

Coordination polymers (CPs) or metal-organic frameworks (MOFs) have attracted considerable attention because of the tunable diversity of structures and functions. A 4,4′-bipyridine molecule, which is a simple, linear, exobidentate, and rigid ligand molecule, can construct two-dimensional (2D) square...

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Detalles Bibliográficos
Autores principales: Kajiro, Hiroshi, Kondo, Atsushi, Kaneko, Katsumi, Kanoh, Hirofumi
Formato: Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International (MDPI) 2010
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2996794/
https://www.ncbi.nlm.nih.gov/pubmed/21152303
http://dx.doi.org/10.3390/ijms11103803
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author Kajiro, Hiroshi
Kondo, Atsushi
Kaneko, Katsumi
Kanoh, Hirofumi
author_facet Kajiro, Hiroshi
Kondo, Atsushi
Kaneko, Katsumi
Kanoh, Hirofumi
author_sort Kajiro, Hiroshi
collection PubMed
description Coordination polymers (CPs) or metal-organic frameworks (MOFs) have attracted considerable attention because of the tunable diversity of structures and functions. A 4,4′-bipyridine molecule, which is a simple, linear, exobidentate, and rigid ligand molecule, can construct two-dimensional (2D) square grid type CPs. Only the 2D-CPs with appropriate metal cations and counter anions exhibit flexibility and adsorb gas with a gate mechanism and these 2D-CPs are called elastic layer-structured metal-organic frameworks (ELMs). Such a unique property can make it possible to overcome the dilemma of strong adsorption and easy desorption, which is one of the ideal properties for practical adsorbents.
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spelling pubmed-29967942010-12-08 Flexible Two-Dimensional Square-Grid Coordination Polymers: Structures and Functions Kajiro, Hiroshi Kondo, Atsushi Kaneko, Katsumi Kanoh, Hirofumi Int J Mol Sci Review Coordination polymers (CPs) or metal-organic frameworks (MOFs) have attracted considerable attention because of the tunable diversity of structures and functions. A 4,4′-bipyridine molecule, which is a simple, linear, exobidentate, and rigid ligand molecule, can construct two-dimensional (2D) square grid type CPs. Only the 2D-CPs with appropriate metal cations and counter anions exhibit flexibility and adsorb gas with a gate mechanism and these 2D-CPs are called elastic layer-structured metal-organic frameworks (ELMs). Such a unique property can make it possible to overcome the dilemma of strong adsorption and easy desorption, which is one of the ideal properties for practical adsorbents. Molecular Diversity Preservation International (MDPI) 2010-09-30 /pmc/articles/PMC2996794/ /pubmed/21152303 http://dx.doi.org/10.3390/ijms11103803 Text en © 2010 by the authors; licensee Molecular Diversity Preservation International, Basel, Switzerland. http://creativecommons.org/licenses/by/3.0 This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Review
Kajiro, Hiroshi
Kondo, Atsushi
Kaneko, Katsumi
Kanoh, Hirofumi
Flexible Two-Dimensional Square-Grid Coordination Polymers: Structures and Functions
title Flexible Two-Dimensional Square-Grid Coordination Polymers: Structures and Functions
title_full Flexible Two-Dimensional Square-Grid Coordination Polymers: Structures and Functions
title_fullStr Flexible Two-Dimensional Square-Grid Coordination Polymers: Structures and Functions
title_full_unstemmed Flexible Two-Dimensional Square-Grid Coordination Polymers: Structures and Functions
title_short Flexible Two-Dimensional Square-Grid Coordination Polymers: Structures and Functions
title_sort flexible two-dimensional square-grid coordination polymers: structures and functions
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2996794/
https://www.ncbi.nlm.nih.gov/pubmed/21152303
http://dx.doi.org/10.3390/ijms11103803
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AT kondoatsushi flexibletwodimensionalsquaregridcoordinationpolymersstructuresandfunctions
AT kanekokatsumi flexibletwodimensionalsquaregridcoordinationpolymersstructuresandfunctions
AT kanohhirofumi flexibletwodimensionalsquaregridcoordinationpolymersstructuresandfunctions

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