Light-induced olefin metathesis

Light activation is a most desirable property for catalysis control. Among the many catalytic processes that may be activated by light, olefin metathesis stands out as both academically motivating and practically useful. Starting from early tungsten heterogeneous photoinitiated metathesis, up to mod...

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Detalles Bibliográficos
Autores principales: Vidavsky, Yuval, Lemcoff, N Gabriel
Formato: Texto
Lenguaje:English
Publicado: Beilstein-Institut 2010
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3002057/
https://www.ncbi.nlm.nih.gov/pubmed/21160912
http://dx.doi.org/10.3762/bjoc.6.127
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author Vidavsky, Yuval
Lemcoff, N Gabriel
author_facet Vidavsky, Yuval
Lemcoff, N Gabriel
author_sort Vidavsky, Yuval
collection PubMed
description Light activation is a most desirable property for catalysis control. Among the many catalytic processes that may be activated by light, olefin metathesis stands out as both academically motivating and practically useful. Starting from early tungsten heterogeneous photoinitiated metathesis, up to modern ruthenium methods based on complex photoisomerisation or indirect photoactivation, this survey of the relevant literature summarises past and present developments in the use of light to expedite olefin ring-closing, ring-opening polymerisation and cross-metathesis reactions.
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spelling pubmed-30020572010-12-15 Light-induced olefin metathesis Vidavsky, Yuval Lemcoff, N Gabriel Beilstein J Org Chem Review Light activation is a most desirable property for catalysis control. Among the many catalytic processes that may be activated by light, olefin metathesis stands out as both academically motivating and practically useful. Starting from early tungsten heterogeneous photoinitiated metathesis, up to modern ruthenium methods based on complex photoisomerisation or indirect photoactivation, this survey of the relevant literature summarises past and present developments in the use of light to expedite olefin ring-closing, ring-opening polymerisation and cross-metathesis reactions. Beilstein-Institut 2010-11-23 /pmc/articles/PMC3002057/ /pubmed/21160912 http://dx.doi.org/10.3762/bjoc.6.127 Text en Copyright © 2010, Vidavsky and Lemcoff https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Review
Vidavsky, Yuval
Lemcoff, N Gabriel
Light-induced olefin metathesis
title Light-induced olefin metathesis
title_full Light-induced olefin metathesis
title_fullStr Light-induced olefin metathesis
title_full_unstemmed Light-induced olefin metathesis
title_short Light-induced olefin metathesis
title_sort light-induced olefin metathesis
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3002057/
https://www.ncbi.nlm.nih.gov/pubmed/21160912
http://dx.doi.org/10.3762/bjoc.6.127
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