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Intramolecular hydroxycarbene C–H-insertion: The curious case of (o-methoxyphenyl)hydroxycarbene

The first C–H insertion of a hydroxycarbene species in the gas phase has been observed experimentally by means of high vacuum flash pyrolysis (HVFP) and subsequent matrix isolation: (o-Methoxyphenyl)glyoxylic acid gives non-isolable (o-methoxyphenyl)hydroxycarbene upon pyrolysis at 600 °C, which rap...

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Detalles Bibliográficos
Autores principales:	Gerbig, Dennis, Ley, David, Reisenauer, Hans Peter, Schreiner, Peter R
Formato:	Texto
Lenguaje:	English
Publicado:	Beilstein-Institut 2010
Materias:	Full Research Paper
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3002070/ https://www.ncbi.nlm.nih.gov/pubmed/21160913 http://dx.doi.org/10.3762/bjoc.6.121

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