N-[(2S)-2-(4-Bromo­phen­yl)-4-oxo-1,3-thia­zolidin-3-yl]pyridine-3-carboxamide

In the title compound, C(15)H(12)BrN(3)O(2)S, the dihedral angle between the pyridine and benzene rings is 73.17 (19)°. The five-membered 1,3-thia­zolidine ring has an envelope conformation, with the S atom displaced by 0.196 (1) Å from the mean plane of the four other ring atoms. An intra­molecular...

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Autores principales: Akkurt, Mehmet, Çelik, Ísmail, Demir, Hale, Özkırımlı, Sumru, Büyükgüngör, Orhan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006680/
https://www.ncbi.nlm.nih.gov/pubmed/21587914
http://dx.doi.org/10.1107/S1600536810022506
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author Akkurt, Mehmet
Çelik, Ísmail
Demir, Hale
Özkırımlı, Sumru
Büyükgüngör, Orhan
author_facet Akkurt, Mehmet
Çelik, Ísmail
Demir, Hale
Özkırımlı, Sumru
Büyükgüngör, Orhan
author_sort Akkurt, Mehmet
collection PubMed
description In the title compound, C(15)H(12)BrN(3)O(2)S, the dihedral angle between the pyridine and benzene rings is 73.17 (19)°. The five-membered 1,3-thia­zolidine ring has an envelope conformation, with the S atom displaced by 0.196 (1) Å from the mean plane of the four other ring atoms. An intra­molecular C—H⋯N inter­action occurs. The crystal structure is stabil­ized by inter­molecular N—H⋯O and C—H⋯O hydrogen bonds and C—H⋯π inter­actions. In addition, a weak π–π stacking inter­action is also observed between the 1,3-thia­zolidine and pyridine rings [centroid–centroid distance = 3.805 (2) Å].
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spelling pubmed-30066802010-12-30 N-[(2S)-2-(4-Bromo­phen­yl)-4-oxo-1,3-thia­zolidin-3-yl]pyridine-3-carboxamide Akkurt, Mehmet Çelik, Ísmail Demir, Hale Özkırımlı, Sumru Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(12)BrN(3)O(2)S, the dihedral angle between the pyridine and benzene rings is 73.17 (19)°. The five-membered 1,3-thia­zolidine ring has an envelope conformation, with the S atom displaced by 0.196 (1) Å from the mean plane of the four other ring atoms. An intra­molecular C—H⋯N inter­action occurs. The crystal structure is stabil­ized by inter­molecular N—H⋯O and C—H⋯O hydrogen bonds and C—H⋯π inter­actions. In addition, a weak π–π stacking inter­action is also observed between the 1,3-thia­zolidine and pyridine rings [centroid–centroid distance = 3.805 (2) Å]. International Union of Crystallography 2010-06-18 /pmc/articles/PMC3006680/ /pubmed/21587914 http://dx.doi.org/10.1107/S1600536810022506 Text en © Akkurt et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Akkurt, Mehmet
Çelik, Ísmail
Demir, Hale
Özkırımlı, Sumru
Büyükgüngör, Orhan
N-[(2S)-2-(4-Bromo­phen­yl)-4-oxo-1,3-thia­zolidin-3-yl]pyridine-3-carboxamide
title N-[(2S)-2-(4-Bromo­phen­yl)-4-oxo-1,3-thia­zolidin-3-yl]pyridine-3-carboxamide
title_full N-[(2S)-2-(4-Bromo­phen­yl)-4-oxo-1,3-thia­zolidin-3-yl]pyridine-3-carboxamide
title_fullStr N-[(2S)-2-(4-Bromo­phen­yl)-4-oxo-1,3-thia­zolidin-3-yl]pyridine-3-carboxamide
title_full_unstemmed N-[(2S)-2-(4-Bromo­phen­yl)-4-oxo-1,3-thia­zolidin-3-yl]pyridine-3-carboxamide
title_short N-[(2S)-2-(4-Bromo­phen­yl)-4-oxo-1,3-thia­zolidin-3-yl]pyridine-3-carboxamide
title_sort n-[(2s)-2-(4-bromo­phen­yl)-4-oxo-1,3-thia­zolidin-3-yl]pyridine-3-carboxamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006680/
https://www.ncbi.nlm.nih.gov/pubmed/21587914
http://dx.doi.org/10.1107/S1600536810022506
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AT ozkırımlısumru n2s24bromophenyl4oxo13thiazolidin3ylpyridine3carboxamide
AT buyukgungororhan n2s24bromophenyl4oxo13thiazolidin3ylpyridine3carboxamide

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