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1,1′-(Ethane-1,2-diyl)bis(indoline-2,3-dione)
The molecule of the title compound, C(18)H(12)N(2)O(4), is situated on a crystallographic centre of symmetry. The molecule has a zigzag structure, with two parallel symmetry-related indoline-2,3-dione fragments linked by an ethylene group at each N atom. In the crystal, the molecules stack in co...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006689/ https://www.ncbi.nlm.nih.gov/pubmed/21587811 http://dx.doi.org/10.1107/S1600536810018957 |
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author | Wang, Yao Cao, Sheng-Li Wan, Chong-Qing Yuan, Jing-Li |
author_facet | Wang, Yao Cao, Sheng-Li Wan, Chong-Qing Yuan, Jing-Li |
author_sort | Wang, Yao |
collection | PubMed |
description | The molecule of the title compound, C(18)H(12)N(2)O(4), is situated on a crystallographic centre of symmetry. The molecule has a zigzag structure, with two parallel symmetry-related indoline-2,3-dione fragments linked by an ethylene group at each N atom. In the crystal, the molecules stack in columns along the b axis. There are two such columns in the structure. The molecules within each column are parallel; however, the molecules in the two columns differ in the respective orientation of the indoline-2,3-dione fragments. In one column, they are approximately parallel to (112), while in the other they are approximately parallel to ([Image: see text]12). The interplanar angle between the indoline-2,3-dione fragments in the two columns is 80.83 (3)°. The molecules within each column are related by mutual displacement of their centres of symmetry, that is (0, ±1/2, ±1/2). The packing between the molecules is provided by weak interactions only, viz. C—H⋯O hydrogen bonds and π–π [centroid–centroid distance = 3.8745 (8) Å] and C=O⋯π interactions. |
format | Text |
id | pubmed-3006689 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30066892010-12-30 1,1′-(Ethane-1,2-diyl)bis(indoline-2,3-dione) Wang, Yao Cao, Sheng-Li Wan, Chong-Qing Yuan, Jing-Li Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecule of the title compound, C(18)H(12)N(2)O(4), is situated on a crystallographic centre of symmetry. The molecule has a zigzag structure, with two parallel symmetry-related indoline-2,3-dione fragments linked by an ethylene group at each N atom. In the crystal, the molecules stack in columns along the b axis. There are two such columns in the structure. The molecules within each column are parallel; however, the molecules in the two columns differ in the respective orientation of the indoline-2,3-dione fragments. In one column, they are approximately parallel to (112), while in the other they are approximately parallel to ([Image: see text]12). The interplanar angle between the indoline-2,3-dione fragments in the two columns is 80.83 (3)°. The molecules within each column are related by mutual displacement of their centres of symmetry, that is (0, ±1/2, ±1/2). The packing between the molecules is provided by weak interactions only, viz. C—H⋯O hydrogen bonds and π–π [centroid–centroid distance = 3.8745 (8) Å] and C=O⋯π interactions. International Union of Crystallography 2010-06-05 /pmc/articles/PMC3006689/ /pubmed/21587811 http://dx.doi.org/10.1107/S1600536810018957 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Wang, Yao Cao, Sheng-Li Wan, Chong-Qing Yuan, Jing-Li 1,1′-(Ethane-1,2-diyl)bis(indoline-2,3-dione) |
title | 1,1′-(Ethane-1,2-diyl)bis(indoline-2,3-dione) |
title_full | 1,1′-(Ethane-1,2-diyl)bis(indoline-2,3-dione) |
title_fullStr | 1,1′-(Ethane-1,2-diyl)bis(indoline-2,3-dione) |
title_full_unstemmed | 1,1′-(Ethane-1,2-diyl)bis(indoline-2,3-dione) |
title_short | 1,1′-(Ethane-1,2-diyl)bis(indoline-2,3-dione) |
title_sort | 1,1′-(ethane-1,2-diyl)bis(indoline-2,3-dione) |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006689/ https://www.ncbi.nlm.nih.gov/pubmed/21587811 http://dx.doi.org/10.1107/S1600536810018957 |
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