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1,1′-(Ethane-1,2-di­yl)bis­(indoline-2,3-dione)

The mol­ecule of the title compound, C(18)H(12)N(2)O(4), is situated on a crystallographic centre of symmetry. The mol­ecule has a zigzag structure, with two parallel symmetry-related indoline-2,3-dione fragments linked by an ethyl­ene group at each N atom. In the crystal, the mol­ecules stack in co...

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Detalles Bibliográficos
Autores principales: Wang, Yao, Cao, Sheng-Li, Wan, Chong-Qing, Yuan, Jing-Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006689/
https://www.ncbi.nlm.nih.gov/pubmed/21587811
http://dx.doi.org/10.1107/S1600536810018957
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author Wang, Yao
Cao, Sheng-Li
Wan, Chong-Qing
Yuan, Jing-Li
author_facet Wang, Yao
Cao, Sheng-Li
Wan, Chong-Qing
Yuan, Jing-Li
author_sort Wang, Yao
collection PubMed
description The mol­ecule of the title compound, C(18)H(12)N(2)O(4), is situated on a crystallographic centre of symmetry. The mol­ecule has a zigzag structure, with two parallel symmetry-related indoline-2,3-dione fragments linked by an ethyl­ene group at each N atom. In the crystal, the mol­ecules stack in columns along the b axis. There are two such columns in the structure. The mol­ecules within each column are parallel; however, the mol­ecules in the two columns differ in the respective orientation of the indoline-2,3-dione fragments. In one column, they are approximately parallel to (112), while in the other they are approximately parallel to ([Image: see text]12). The inter­planar angle between the indoline-2,3-dione fragments in the two columns is 80.83 (3)°. The mol­ecules within each column are related by mutual displacement of their centres of symmetry, that is (0, ±1/2, ±1/2). The packing between the mol­ecules is provided by weak inter­actions only, viz. C—H⋯O hydrogen bonds and π–π [centroid–centroid distance = 3.8745 (8) Å] and C=O⋯π inter­actions.
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spelling pubmed-30066892010-12-30 1,1′-(Ethane-1,2-di­yl)bis­(indoline-2,3-dione) Wang, Yao Cao, Sheng-Li Wan, Chong-Qing Yuan, Jing-Li Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(18)H(12)N(2)O(4), is situated on a crystallographic centre of symmetry. The mol­ecule has a zigzag structure, with two parallel symmetry-related indoline-2,3-dione fragments linked by an ethyl­ene group at each N atom. In the crystal, the mol­ecules stack in columns along the b axis. There are two such columns in the structure. The mol­ecules within each column are parallel; however, the mol­ecules in the two columns differ in the respective orientation of the indoline-2,3-dione fragments. In one column, they are approximately parallel to (112), while in the other they are approximately parallel to ([Image: see text]12). The inter­planar angle between the indoline-2,3-dione fragments in the two columns is 80.83 (3)°. The mol­ecules within each column are related by mutual displacement of their centres of symmetry, that is (0, ±1/2, ±1/2). The packing between the mol­ecules is provided by weak inter­actions only, viz. C—H⋯O hydrogen bonds and π–π [centroid–centroid distance = 3.8745 (8) Å] and C=O⋯π inter­actions. International Union of Crystallography 2010-06-05 /pmc/articles/PMC3006689/ /pubmed/21587811 http://dx.doi.org/10.1107/S1600536810018957 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wang, Yao
Cao, Sheng-Li
Wan, Chong-Qing
Yuan, Jing-Li
1,1′-(Ethane-1,2-di­yl)bis­(indoline-2,3-dione)
title 1,1′-(Ethane-1,2-di­yl)bis­(indoline-2,3-dione)
title_full 1,1′-(Ethane-1,2-di­yl)bis­(indoline-2,3-dione)
title_fullStr 1,1′-(Ethane-1,2-di­yl)bis­(indoline-2,3-dione)
title_full_unstemmed 1,1′-(Ethane-1,2-di­yl)bis­(indoline-2,3-dione)
title_short 1,1′-(Ethane-1,2-di­yl)bis­(indoline-2,3-dione)
title_sort 1,1′-(ethane-1,2-di­yl)bis­(indoline-2,3-dione)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006689/
https://www.ncbi.nlm.nih.gov/pubmed/21587811
http://dx.doi.org/10.1107/S1600536810018957
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