Cargando…
2-(4-Fluorophenyl)-5-iodo-7-methyl-3-methylsulfinyl-1-benzofuran
In the title compound, C(16)H(12)FIO(2)S, the O atom and the methyl group of the methylsulfinyl substituent lie on opposite sides of the plane through the benzofuran fragment. The 4-fluorophenyl ring is rotated slightly out of the benzofuran plane, as indicated by the dihedral angle of 7.43 (6)°....
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006691/ https://www.ncbi.nlm.nih.gov/pubmed/21587905 http://dx.doi.org/10.1107/S1600536810022397 |
Sumario: | In the title compound, C(16)H(12)FIO(2)S, the O atom and the methyl group of the methylsulfinyl substituent lie on opposite sides of the plane through the benzofuran fragment. The 4-fluorophenyl ring is rotated slightly out of the benzofuran plane, as indicated by the dihedral angle of 7.43 (6)°. In the crystal structure, pairs of short I⋯O [3.074 (2) Å] contacts link the molecules into centrosymmetric dimers. These dimers are further linked via aromatic π–π interactions between the benzene and the 4-fluorophenyl rings of neighbouring molecules [centroid–centroid distance = 3.617 (3) Å]. |
---|