3′,4′-Dichloro­biphenyl-4-yl 2,2,2-trichloro­ethyl sulfate

The four independent mol­ecules in the asymmetric unit of the title compound, C(14)H(9)Cl(5)O(4)S, are related by pseudo-inversion centres. The mol­ecules have C(aromatic)—O bond lengths ranging from 1.426 (10) to 1.449 (9) Å and biphenyl-4-yl sulfate ester bond lengths ranging from 1.563 (6) to 1.5...

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Detalles Bibliográficos
Autores principales: Li, Xueshu, Parkin, Sean, Duffel, Michael W., Robertson, Larry W., Lehmler, Hans-Joachim
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006693/
https://www.ncbi.nlm.nih.gov/pubmed/21587847
http://dx.doi.org/10.1107/S1600536810020362
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author Li, Xueshu
Parkin, Sean
Duffel, Michael W.
Robertson, Larry W.
Lehmler, Hans-Joachim
author_facet Li, Xueshu
Parkin, Sean
Duffel, Michael W.
Robertson, Larry W.
Lehmler, Hans-Joachim
author_sort Li, Xueshu
collection PubMed
description The four independent mol­ecules in the asymmetric unit of the title compound, C(14)H(9)Cl(5)O(4)S, are related by pseudo-inversion centres. The mol­ecules have C(aromatic)—O bond lengths ranging from 1.426 (10) to 1.449 (9) Å and biphenyl-4-yl sulfate ester bond lengths ranging from 1.563 (6) to 1.586 (6) Å, which is comparable to structurally related sulfuric acid diesters. The dihedral angles between the benzene rings range from 22.5 (4) to 29.1 (4)° and are significantly smaller than the calculated dihedral angle of 41.2°.
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spelling pubmed-30066932010-12-30 3′,4′-Dichloro­biphenyl-4-yl 2,2,2-trichloro­ethyl sulfate Li, Xueshu Parkin, Sean Duffel, Michael W. Robertson, Larry W. Lehmler, Hans-Joachim Acta Crystallogr Sect E Struct Rep Online Organic Papers The four independent mol­ecules in the asymmetric unit of the title compound, C(14)H(9)Cl(5)O(4)S, are related by pseudo-inversion centres. The mol­ecules have C(aromatic)—O bond lengths ranging from 1.426 (10) to 1.449 (9) Å and biphenyl-4-yl sulfate ester bond lengths ranging from 1.563 (6) to 1.586 (6) Å, which is comparable to structurally related sulfuric acid diesters. The dihedral angles between the benzene rings range from 22.5 (4) to 29.1 (4)° and are significantly smaller than the calculated dihedral angle of 41.2°. International Union of Crystallography 2010-06-09 /pmc/articles/PMC3006693/ /pubmed/21587847 http://dx.doi.org/10.1107/S1600536810020362 Text en © Li et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Xueshu
Parkin, Sean
Duffel, Michael W.
Robertson, Larry W.
Lehmler, Hans-Joachim
3′,4′-Dichloro­biphenyl-4-yl 2,2,2-trichloro­ethyl sulfate
title 3′,4′-Dichloro­biphenyl-4-yl 2,2,2-trichloro­ethyl sulfate
title_full 3′,4′-Dichloro­biphenyl-4-yl 2,2,2-trichloro­ethyl sulfate
title_fullStr 3′,4′-Dichloro­biphenyl-4-yl 2,2,2-trichloro­ethyl sulfate
title_full_unstemmed 3′,4′-Dichloro­biphenyl-4-yl 2,2,2-trichloro­ethyl sulfate
title_short 3′,4′-Dichloro­biphenyl-4-yl 2,2,2-trichloro­ethyl sulfate
title_sort 3′,4′-dichloro­biphenyl-4-yl 2,2,2-trichloro­ethyl sulfate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006693/
https://www.ncbi.nlm.nih.gov/pubmed/21587847
http://dx.doi.org/10.1107/S1600536810020362
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AT duffelmichaelw 34dichlorobiphenyl4yl222trichloroethylsulfate
AT robertsonlarryw 34dichlorobiphenyl4yl222trichloroethylsulfate
AT lehmlerhansjoachim 34dichlorobiphenyl4yl222trichloroethylsulfate

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