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2-Amino-4-methyl­pyridinium 3-chloro­benzoate

In the title salt, C(6)H(9)N(2) (+)·C(7)H(4)ClO(2) (−), the 2-amino-4-methyl­pyridinium cation is almost planar, with a maximum deviation of 0.010 (1) Å. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxyl­ate O atoms of the anion via a pair...

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Detalles Bibliográficos
Autores principales: Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006694/
https://www.ncbi.nlm.nih.gov/pubmed/21588043
http://dx.doi.org/10.1107/S160053681002444X
Descripción
Sumario:In the title salt, C(6)H(9)N(2) (+)·C(7)H(4)ClO(2) (−), the 2-amino-4-methyl­pyridinium cation is almost planar, with a maximum deviation of 0.010 (1) Å. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxyl­ate O atoms of the anion via a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The ion pairs are further connected via N—H⋯O and C—H⋯O hydrogen bonds, forming a two-dimensional network parallel to the bc plane.