2-Amino-4-methyl­pyridinium 3-chloro­benzoate

In the title salt, C(6)H(9)N(2) (+)·C(7)H(4)ClO(2) (−), the 2-amino-4-methyl­pyridinium cation is almost planar, with a maximum deviation of 0.010 (1) Å. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxyl­ate O atoms of the anion via a pair...

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Detalles Bibliográficos
Autores principales: Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006694/
https://www.ncbi.nlm.nih.gov/pubmed/21588043
http://dx.doi.org/10.1107/S160053681002444X
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author Hemamalini, Madhukar
Fun, Hoong-Kun
author_facet Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Hemamalini, Madhukar
collection PubMed
description In the title salt, C(6)H(9)N(2) (+)·C(7)H(4)ClO(2) (−), the 2-amino-4-methyl­pyridinium cation is almost planar, with a maximum deviation of 0.010 (1) Å. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxyl­ate O atoms of the anion via a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The ion pairs are further connected via N—H⋯O and C—H⋯O hydrogen bonds, forming a two-dimensional network parallel to the bc plane.
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spelling pubmed-30066942010-12-30 2-Amino-4-methyl­pyridinium 3-chloro­benzoate Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(6)H(9)N(2) (+)·C(7)H(4)ClO(2) (−), the 2-amino-4-methyl­pyridinium cation is almost planar, with a maximum deviation of 0.010 (1) Å. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxyl­ate O atoms of the anion via a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The ion pairs are further connected via N—H⋯O and C—H⋯O hydrogen bonds, forming a two-dimensional network parallel to the bc plane. International Union of Crystallography 2010-06-26 /pmc/articles/PMC3006694/ /pubmed/21588043 http://dx.doi.org/10.1107/S160053681002444X Text en © Hemamalini and Fun 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hemamalini, Madhukar
Fun, Hoong-Kun
2-Amino-4-methyl­pyridinium 3-chloro­benzoate
title 2-Amino-4-methyl­pyridinium 3-chloro­benzoate
title_full 2-Amino-4-methyl­pyridinium 3-chloro­benzoate
title_fullStr 2-Amino-4-methyl­pyridinium 3-chloro­benzoate
title_full_unstemmed 2-Amino-4-methyl­pyridinium 3-chloro­benzoate
title_short 2-Amino-4-methyl­pyridinium 3-chloro­benzoate
title_sort 2-amino-4-methyl­pyridinium 3-chloro­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006694/
https://www.ncbi.nlm.nih.gov/pubmed/21588043
http://dx.doi.org/10.1107/S160053681002444X
work_keys_str_mv AT hemamalinimadhukar 2amino4methylpyridinium3chlorobenzoate
AT funhoongkun 2amino4methylpyridinium3chlorobenzoate

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