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μ(3)-Oxido-tris{dichlorido[1,3-bis(1,3,5-trimethylphenyl)imidazol-2-ylidene]gold(III)} bis(trifluoromethanesulfonyl)imide–[bis(trifluoromethanesulfonyl)imide]silver(I) (1/2)
The unusual trinuclear Au(III) oxide title complex, [Au(3)Cl(6)O(C(21)H(24)N(2))(3)](C(2)F(6)NO(4)S(2))·2[Ag(C(2)F(6)NO(4)S(2))], is the side product of the reaction of [1,3-bis(1,3,5-trimethylphenyl)imidazol-2-ylidene]dichloridophenylgold(III) with silver bis(trifluoromethanesulfonyl)imide...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006696/ https://www.ncbi.nlm.nih.gov/pubmed/21587670 http://dx.doi.org/10.1107/S160053681001994X |
Sumario: | The unusual trinuclear Au(III) oxide title complex, [Au(3)Cl(6)O(C(21)H(24)N(2))(3)](C(2)F(6)NO(4)S(2))·2[Ag(C(2)F(6)NO(4)S(2))], is the side product of the reaction of [1,3-bis(1,3,5-trimethylphenyl)imidazol-2-ylidene]dichloridophenylgold(III) with silver bis(trifluoromethanesulfonyl)imide in the presence of traces of water. In contrast to corresponding Au(I) complexes, the core structure of the title compound is planar. Two silver(I) bis(trifluoromethanesulfonyl)imide units are loosely bound to the complex cation. Here the silver atoms, disordered over two positions in a 0.870 (2):0.130 (2) ratio, interact either with the lone pairs of three chlorine ligands or two chlorine ligands and one edge of the mesityl π-system. The crystal under investigation was a partial racemic twin. |
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