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6,7-Dihydro-3H-1,4-diazepino[1,2,3,4-lmn][1,10]phenanthroline-3,9(5H)-dione
In the title compound, C(15)H(12)N(2)O(2), the seven-membered ring bearing the three methylene C atoms displays a puckered conformation, with the methylene C atoms deviating from the plane of the benzene ring by 0.05 (1), 0.98 (1) and 1.04 (1) Å. The phenanthroline unit is not planar; the dihedral...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006698/ https://www.ncbi.nlm.nih.gov/pubmed/21588051 http://dx.doi.org/10.1107/S1600536810024761 |
Sumario: | In the title compound, C(15)H(12)N(2)O(2), the seven-membered ring bearing the three methylene C atoms displays a puckered conformation, with the methylene C atoms deviating from the plane of the benzene ring by 0.05 (1), 0.98 (1) and 1.04 (1) Å. The phenanthroline unit is not planar; the dihedral angles between this benzene ring and the other pyridyl rings are 9.62 (4) and 9.31 (4)°. The crystal packing is stabilized by π–π interactions between two phenanthroline ring systems, forming a centrosymmetric dimer with a centroid–centroid distance of 3.656 (1) Å. |
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