Conformation and absolute configuration of (1S,2S)-2-(phenyl­selan­yl)cyclo­hexyl (R)-2-meth­oxy-2-(1-naphth­yl)propionate

The relative and absolute configurations of the title compound, C(26)H(28)O(3)Se, were assigned from the known configuration of (R)-(−)-2-meth­oxy-2-(1-naphth­yl)propionic acid used as starting material, and by examination of the Bijvoet (Friedel) pairs, using the anomalous dispersion data collected...

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Autores principales: Murakami, Satoshi, Kato, Akane, Katagiri, Hiroshi, Matsumoto, Takatoshi, Kijima, Tatsuro
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006699/
https://www.ncbi.nlm.nih.gov/pubmed/21587902
http://dx.doi.org/10.1107/S1600536810022233
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author Murakami, Satoshi
Kato, Akane
Katagiri, Hiroshi
Matsumoto, Takatoshi
Kijima, Tatsuro
author_facet Murakami, Satoshi
Kato, Akane
Katagiri, Hiroshi
Matsumoto, Takatoshi
Kijima, Tatsuro
author_sort Murakami, Satoshi
collection PubMed
description The relative and absolute configurations of the title compound, C(26)H(28)O(3)Se, were assigned from the known configuration of (R)-(−)-2-meth­oxy-2-(1-naphth­yl)propionic acid used as starting material, and by examination of the Bijvoet (Friedel) pairs, using the anomalous dispersion data collected with Mo Kα radiation at low temperature. The geometry around the carbonyl group exists in the syn conformation, as reflected in torsion angles involving this group, and the stability of the structure is affected by weak bifurcated intra­molecular C—H⋯O hydrogen bonds.
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spelling pubmed-30066992010-12-30 Conformation and absolute configuration of (1S,2S)-2-(phenyl­selan­yl)cyclo­hexyl (R)-2-meth­oxy-2-(1-naphth­yl)propionate Murakami, Satoshi Kato, Akane Katagiri, Hiroshi Matsumoto, Takatoshi Kijima, Tatsuro Acta Crystallogr Sect E Struct Rep Online Organic Papers The relative and absolute configurations of the title compound, C(26)H(28)O(3)Se, were assigned from the known configuration of (R)-(−)-2-meth­oxy-2-(1-naphth­yl)propionic acid used as starting material, and by examination of the Bijvoet (Friedel) pairs, using the anomalous dispersion data collected with Mo Kα radiation at low temperature. The geometry around the carbonyl group exists in the syn conformation, as reflected in torsion angles involving this group, and the stability of the structure is affected by weak bifurcated intra­molecular C—H⋯O hydrogen bonds. International Union of Crystallography 2010-06-16 /pmc/articles/PMC3006699/ /pubmed/21587902 http://dx.doi.org/10.1107/S1600536810022233 Text en © Murakami et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Murakami, Satoshi
Kato, Akane
Katagiri, Hiroshi
Matsumoto, Takatoshi
Kijima, Tatsuro
Conformation and absolute configuration of (1S,2S)-2-(phenyl­selan­yl)cyclo­hexyl (R)-2-meth­oxy-2-(1-naphth­yl)propionate
title Conformation and absolute configuration of (1S,2S)-2-(phenyl­selan­yl)cyclo­hexyl (R)-2-meth­oxy-2-(1-naphth­yl)propionate
title_full Conformation and absolute configuration of (1S,2S)-2-(phenyl­selan­yl)cyclo­hexyl (R)-2-meth­oxy-2-(1-naphth­yl)propionate
title_fullStr Conformation and absolute configuration of (1S,2S)-2-(phenyl­selan­yl)cyclo­hexyl (R)-2-meth­oxy-2-(1-naphth­yl)propionate
title_full_unstemmed Conformation and absolute configuration of (1S,2S)-2-(phenyl­selan­yl)cyclo­hexyl (R)-2-meth­oxy-2-(1-naphth­yl)propionate
title_short Conformation and absolute configuration of (1S,2S)-2-(phenyl­selan­yl)cyclo­hexyl (R)-2-meth­oxy-2-(1-naphth­yl)propionate
title_sort conformation and absolute configuration of (1s,2s)-2-(phenyl­selan­yl)cyclo­hexyl (r)-2-meth­oxy-2-(1-naphth­yl)propionate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006699/
https://www.ncbi.nlm.nih.gov/pubmed/21587902
http://dx.doi.org/10.1107/S1600536810022233
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