Tripyridinium cis-tetra­chlorido­dioxido­molybdate(VI) chloride

In the title compound, (C(5)H(6)N)(3)[MoCl(4)O(2)]Cl, the pyridinium cations are N—H⋯Cl hydrogen bonded to the anionic [MoCl(4)O(2)](2−) complexes and to the two crystallographically independent chloride anions (located on C2 axes). The Mo(6+) centre adopts a highly distorted octa­hedral geometry, b...

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Autores principales: Fernandes, José A., Gomes, Ana C., Figueiredo, Sónia, Gago, Sandra, Ribeiro-Claro, Paulo J. A., Gonçalves, Isabel S., Almeida Paz, Filipe A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006702/
https://www.ncbi.nlm.nih.gov/pubmed/21587767
http://dx.doi.org/10.1107/S1600536810023950
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author Fernandes, José A.
Gomes, Ana C.
Figueiredo, Sónia
Gago, Sandra
Ribeiro-Claro, Paulo J. A.
Gonçalves, Isabel S.
Almeida Paz, Filipe A.
author_facet Fernandes, José A.
Gomes, Ana C.
Figueiredo, Sónia
Gago, Sandra
Ribeiro-Claro, Paulo J. A.
Gonçalves, Isabel S.
Almeida Paz, Filipe A.
author_sort Fernandes, José A.
collection PubMed
description In the title compound, (C(5)H(6)N)(3)[MoCl(4)O(2)]Cl, the pyridinium cations are N—H⋯Cl hydrogen bonded to the anionic [MoCl(4)O(2)](2−) complexes and to the two crystallographically independent chloride anions (located on C2 axes). The Mo(6+) centre adopts a highly distorted octa­hedral geometry, being surrounded by four chloride and two terminal oxide groups. The oxide ligands are mutually cis.
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spelling pubmed-30067022010-12-30 Tripyridinium cis-tetra­chlorido­dioxido­molybdate(VI) chloride Fernandes, José A. Gomes, Ana C. Figueiredo, Sónia Gago, Sandra Ribeiro-Claro, Paulo J. A. Gonçalves, Isabel S. Almeida Paz, Filipe A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(5)H(6)N)(3)[MoCl(4)O(2)]Cl, the pyridinium cations are N—H⋯Cl hydrogen bonded to the anionic [MoCl(4)O(2)](2−) complexes and to the two crystallographically independent chloride anions (located on C2 axes). The Mo(6+) centre adopts a highly distorted octa­hedral geometry, being surrounded by four chloride and two terminal oxide groups. The oxide ligands are mutually cis. International Union of Crystallography 2010-06-26 /pmc/articles/PMC3006702/ /pubmed/21587767 http://dx.doi.org/10.1107/S1600536810023950 Text en © Fernandes et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fernandes, José A.
Gomes, Ana C.
Figueiredo, Sónia
Gago, Sandra
Ribeiro-Claro, Paulo J. A.
Gonçalves, Isabel S.
Almeida Paz, Filipe A.
Tripyridinium cis-tetra­chlorido­dioxido­molybdate(VI) chloride
title Tripyridinium cis-tetra­chlorido­dioxido­molybdate(VI) chloride
title_full Tripyridinium cis-tetra­chlorido­dioxido­molybdate(VI) chloride
title_fullStr Tripyridinium cis-tetra­chlorido­dioxido­molybdate(VI) chloride
title_full_unstemmed Tripyridinium cis-tetra­chlorido­dioxido­molybdate(VI) chloride
title_short Tripyridinium cis-tetra­chlorido­dioxido­molybdate(VI) chloride
title_sort tripyridinium cis-tetra­chlorido­dioxido­molybdate(vi) chloride
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006702/
https://www.ncbi.nlm.nih.gov/pubmed/21587767
http://dx.doi.org/10.1107/S1600536810023950
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