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(2-Methoxybenzyl)(2-methoxybenzylidene)azanium (2-methoxyphenyl)methanaminium tetrachloridozincate(II) monohydrate
The title compound, (C(8)H(12)NO)(C(16)H(18)NO(2))[ZnCl(4)]·H(2)O, was obtained as a by-product of the Zn(2+) and HCl catalyzed condensation of (2-methoxyphenyl)methanamine in water. Both cations feature an intramolecular N—H⋯O hydrogen bond. In the crystal, the components are linked by an exten...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006710/ https://www.ncbi.nlm.nih.gov/pubmed/21587715 http://dx.doi.org/10.1107/S1600536810021793 |
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author | El Glaoui, Meher Jeanneau, Erwann Zeller, Matthias Lefebvre, Frederic Ben Nasr, Cherif |
author_facet | El Glaoui, Meher Jeanneau, Erwann Zeller, Matthias Lefebvre, Frederic Ben Nasr, Cherif |
author_sort | El Glaoui, Meher |
collection | PubMed |
description | The title compound, (C(8)H(12)NO)(C(16)H(18)NO(2))[ZnCl(4)]·H(2)O, was obtained as a by-product of the Zn(2+) and HCl catalyzed condensation of (2-methoxyphenyl)methanamine in water. Both cations feature an intramolecular N—H⋯O hydrogen bond. In the crystal, the components are linked by an extensive three-dimensional network of N—H⋯O, O—H⋯Cl and N—H⋯Cl hydrogen bonds (three of them bifurcated). Weak C—H⋯O interactions also occur. |
format | Text |
id | pubmed-3006710 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30067102010-12-30 (2-Methoxybenzyl)(2-methoxybenzylidene)azanium (2-methoxyphenyl)methanaminium tetrachloridozincate(II) monohydrate El Glaoui, Meher Jeanneau, Erwann Zeller, Matthias Lefebvre, Frederic Ben Nasr, Cherif Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(8)H(12)NO)(C(16)H(18)NO(2))[ZnCl(4)]·H(2)O, was obtained as a by-product of the Zn(2+) and HCl catalyzed condensation of (2-methoxyphenyl)methanamine in water. Both cations feature an intramolecular N—H⋯O hydrogen bond. In the crystal, the components are linked by an extensive three-dimensional network of N—H⋯O, O—H⋯Cl and N—H⋯Cl hydrogen bonds (three of them bifurcated). Weak C—H⋯O interactions also occur. International Union of Crystallography 2010-06-16 /pmc/articles/PMC3006710/ /pubmed/21587715 http://dx.doi.org/10.1107/S1600536810021793 Text en © El Glaoui et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers El Glaoui, Meher Jeanneau, Erwann Zeller, Matthias Lefebvre, Frederic Ben Nasr, Cherif (2-Methoxybenzyl)(2-methoxybenzylidene)azanium (2-methoxyphenyl)methanaminium tetrachloridozincate(II) monohydrate |
title | (2-Methoxybenzyl)(2-methoxybenzylidene)azanium (2-methoxyphenyl)methanaminium tetrachloridozincate(II) monohydrate |
title_full | (2-Methoxybenzyl)(2-methoxybenzylidene)azanium (2-methoxyphenyl)methanaminium tetrachloridozincate(II) monohydrate |
title_fullStr | (2-Methoxybenzyl)(2-methoxybenzylidene)azanium (2-methoxyphenyl)methanaminium tetrachloridozincate(II) monohydrate |
title_full_unstemmed | (2-Methoxybenzyl)(2-methoxybenzylidene)azanium (2-methoxyphenyl)methanaminium tetrachloridozincate(II) monohydrate |
title_short | (2-Methoxybenzyl)(2-methoxybenzylidene)azanium (2-methoxyphenyl)methanaminium tetrachloridozincate(II) monohydrate |
title_sort | (2-methoxybenzyl)(2-methoxybenzylidene)azanium (2-methoxyphenyl)methanaminium tetrachloridozincate(ii) monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006710/ https://www.ncbi.nlm.nih.gov/pubmed/21587715 http://dx.doi.org/10.1107/S1600536810021793 |
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