4-[(E)-({4-[Bis­(2-hy­droxy­eth­yl)amino]­phen­yl}imino)­meth­yl]phenol

In the title compound, C(17)H(20)N(2)O(3), the amino N atom is in a planar environment (sum of angles = 360.0°). All hy­droxy H atoms are involved in hydrogen bonding. In the crystal structure, two O—H⋯O and an O—H⋯N(imino) hydrogen bond result in the formation of a three-dimensional network. The la...

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Detalles Bibliográficos
Autores principales: Liu, Xiaoju, Yang, Bingqin, Borzov, Maxim V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006715/
https://www.ncbi.nlm.nih.gov/pubmed/21587874
http://dx.doi.org/10.1107/S1600536810021926
Descripción
Sumario:In the title compound, C(17)H(20)N(2)O(3), the amino N atom is in a planar environment (sum of angles = 360.0°). All hy­droxy H atoms are involved in hydrogen bonding. In the crystal structure, two O—H⋯O and an O—H⋯N(imino) hydrogen bond result in the formation of a three-dimensional network. The latter hydrogen bonding causes distortion of the planarity of the 4-HO–C(6)H(4)–CH=N–C(6)H(4)– fragment by rotation around the =N—C(Ph) bond. The crystal studied was a non-merohedral twin [refined BASF parameter for the major component = 0.5293 (7)].

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