4-[(E)-({4-[Bis­(2-hy­droxy­eth­yl)amino]­phen­yl}imino)­meth­yl]phenol

In the title compound, C(17)H(20)N(2)O(3), the amino N atom is in a planar environment (sum of angles = 360.0°). All hy­droxy H atoms are involved in hydrogen bonding. In the crystal structure, two O—H⋯O and an O—H⋯N(imino) hydrogen bond result in the formation of a three-dimensional network. The la...

Descripción completa

Detalles Bibliográficos
Autores principales: Liu, Xiaoju, Yang, Bingqin, Borzov, Maxim V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006715/
https://www.ncbi.nlm.nih.gov/pubmed/21587874
http://dx.doi.org/10.1107/S1600536810021926
_version_ 1782194204477227008
author Liu, Xiaoju
Yang, Bingqin
Borzov, Maxim V.
author_facet Liu, Xiaoju
Yang, Bingqin
Borzov, Maxim V.
author_sort Liu, Xiaoju
collection PubMed
description In the title compound, C(17)H(20)N(2)O(3), the amino N atom is in a planar environment (sum of angles = 360.0°). All hy­droxy H atoms are involved in hydrogen bonding. In the crystal structure, two O—H⋯O and an O—H⋯N(imino) hydrogen bond result in the formation of a three-dimensional network. The latter hydrogen bonding causes distortion of the planarity of the 4-HO–C(6)H(4)–CH=N–C(6)H(4)– fragment by rotation around the =N—C(Ph) bond. The crystal studied was a non-merohedral twin [refined BASF parameter for the major component = 0.5293 (7)].
format Text
id pubmed-3006715
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30067152010-12-30 4-[(E)-({4-[Bis­(2-hy­droxy­eth­yl)amino]­phen­yl}imino)­meth­yl]phenol Liu, Xiaoju Yang, Bingqin Borzov, Maxim V. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(20)N(2)O(3), the amino N atom is in a planar environment (sum of angles = 360.0°). All hy­droxy H atoms are involved in hydrogen bonding. In the crystal structure, two O—H⋯O and an O—H⋯N(imino) hydrogen bond result in the formation of a three-dimensional network. The latter hydrogen bonding causes distortion of the planarity of the 4-HO–C(6)H(4)–CH=N–C(6)H(4)– fragment by rotation around the =N—C(Ph) bond. The crystal studied was a non-merohedral twin [refined BASF parameter for the major component = 0.5293 (7)]. International Union of Crystallography 2010-06-16 /pmc/articles/PMC3006715/ /pubmed/21587874 http://dx.doi.org/10.1107/S1600536810021926 Text en © Liu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liu, Xiaoju
Yang, Bingqin
Borzov, Maxim V.
4-[(E)-({4-[Bis­(2-hy­droxy­eth­yl)amino]­phen­yl}imino)­meth­yl]phenol
title 4-[(E)-({4-[Bis­(2-hy­droxy­eth­yl)amino]­phen­yl}imino)­meth­yl]phenol
title_full 4-[(E)-({4-[Bis­(2-hy­droxy­eth­yl)amino]­phen­yl}imino)­meth­yl]phenol
title_fullStr 4-[(E)-({4-[Bis­(2-hy­droxy­eth­yl)amino]­phen­yl}imino)­meth­yl]phenol
title_full_unstemmed 4-[(E)-({4-[Bis­(2-hy­droxy­eth­yl)amino]­phen­yl}imino)­meth­yl]phenol
title_short 4-[(E)-({4-[Bis­(2-hy­droxy­eth­yl)amino]­phen­yl}imino)­meth­yl]phenol
title_sort 4-[(e)-({4-[bis­(2-hy­droxy­eth­yl)amino]­phen­yl}imino)­meth­yl]phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006715/
https://www.ncbi.nlm.nih.gov/pubmed/21587874
http://dx.doi.org/10.1107/S1600536810021926
work_keys_str_mv AT liuxiaoju 4e4bis2hydroxyethylaminophenyliminomethylphenol
AT yangbingqin 4e4bis2hydroxyethylaminophenyliminomethylphenol
AT borzovmaximv 4e4bis2hydroxyethylaminophenyliminomethylphenol

Ejemplares similares