2-(2,3,4,9-Tetra­hydro-1H-carbazol-1-ylidene)propane­dinitrile

In the title mol­ecule, C(15)H(11)N(3), the dihedral angle between the benzene ring and the fused pyrrole ring is 1.07 (5)°. The cyclo­hexene ring adopts an envelope conformation: the dicyano­methyl­ene group at position 1 has a coplanar orientation. An intra­molecular N—H⋯N hydrogen bond generates...

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Detalles Bibliográficos
Autores principales: Archana, R., Prabakaran, K., Rajendra Prasad, K. J., Thiruvalluvar, A., Butcher, R. J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006716/
https://www.ncbi.nlm.nih.gov/pubmed/21587930
http://dx.doi.org/10.1107/S1600536810022671
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author Archana, R.
Prabakaran, K.
Rajendra Prasad, K. J.
Thiruvalluvar, A.
Butcher, R. J.
author_facet Archana, R.
Prabakaran, K.
Rajendra Prasad, K. J.
Thiruvalluvar, A.
Butcher, R. J.
author_sort Archana, R.
collection PubMed
description In the title mol­ecule, C(15)H(11)N(3), the dihedral angle between the benzene ring and the fused pyrrole ring is 1.07 (5)°. The cyclo­hexene ring adopts an envelope conformation: the dicyano­methyl­ene group at position 1 has a coplanar orientation. An intra­molecular N—H⋯N hydrogen bond generates an S(7) ring motif. Inter­molecular N—H⋯N hydrogen bonds form an R (2) (2)(14) ring in the crystal. A C—H⋯π inter­action involving the benzene ring is also found in the structure.
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spelling pubmed-30067162010-12-30 2-(2,3,4,9-Tetra­hydro-1H-carbazol-1-ylidene)propane­dinitrile Archana, R. Prabakaran, K. Rajendra Prasad, K. J. Thiruvalluvar, A. Butcher, R. J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(15)H(11)N(3), the dihedral angle between the benzene ring and the fused pyrrole ring is 1.07 (5)°. The cyclo­hexene ring adopts an envelope conformation: the dicyano­methyl­ene group at position 1 has a coplanar orientation. An intra­molecular N—H⋯N hydrogen bond generates an S(7) ring motif. Inter­molecular N—H⋯N hydrogen bonds form an R (2) (2)(14) ring in the crystal. A C—H⋯π inter­action involving the benzene ring is also found in the structure. International Union of Crystallography 2010-06-18 /pmc/articles/PMC3006716/ /pubmed/21587930 http://dx.doi.org/10.1107/S1600536810022671 Text en © Archana et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Archana, R.
Prabakaran, K.
Rajendra Prasad, K. J.
Thiruvalluvar, A.
Butcher, R. J.
2-(2,3,4,9-Tetra­hydro-1H-carbazol-1-ylidene)propane­dinitrile
title 2-(2,3,4,9-Tetra­hydro-1H-carbazol-1-ylidene)propane­dinitrile
title_full 2-(2,3,4,9-Tetra­hydro-1H-carbazol-1-ylidene)propane­dinitrile
title_fullStr 2-(2,3,4,9-Tetra­hydro-1H-carbazol-1-ylidene)propane­dinitrile
title_full_unstemmed 2-(2,3,4,9-Tetra­hydro-1H-carbazol-1-ylidene)propane­dinitrile
title_short 2-(2,3,4,9-Tetra­hydro-1H-carbazol-1-ylidene)propane­dinitrile
title_sort 2-(2,3,4,9-tetra­hydro-1h-carbazol-1-ylidene)propane­dinitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006716/
https://www.ncbi.nlm.nih.gov/pubmed/21587930
http://dx.doi.org/10.1107/S1600536810022671
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