Ammonium [(1S)-(endo,anti)]-(−)-3-bromo­camphor-8-sulfonate

In the title mol­ecular salt, NH(4) (+)·C(10)H(14)BrO(4)S(−), the norbornane skeleton of the anion is composed of two five-membered rings in envelope conformations and a six-membered ring with one Br atom, one carbonyl O atom and a methyl group held in a boat conformation by a bridging methyl­ene gr...

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Detalles Bibliográficos
Autores principales: Abbasi, Muhammad Athar, Aziz-ur-Rehman, Akkurt, Mehmet, Jahangir, Muhammad, Ng, Seik Weng, Khan, Islam Ullah
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006721/
https://www.ncbi.nlm.nih.gov/pubmed/21587927
http://dx.doi.org/10.1107/S1600536810022804
Descripción
Sumario:In the title mol­ecular salt, NH(4) (+)·C(10)H(14)BrO(4)S(−), the norbornane skeleton of the anion is composed of two five-membered rings in envelope conformations and a six-membered ring with one Br atom, one carbonyl O atom and a methyl group held in a boat conformation by a bridging methyl­ene group. Short intra­molecular C—H⋯O and C—H⋯Br inter­actions occur. In the crystal, the component ions are linked by inter­molecular N—H⋯O and C—H⋯O hydrogen bonds.

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