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(E)-N′-(5-Bromo-2-hydroxybenzylidene)-2-methoxybenzohydrazide
In the title compound, C(15)H(13)BrN(2)O(3), the molecule adopts an E configuration about the C=N bond and the two benzene rings form a dihedral angle of 20.3 (3)°. In the molecule, there are two intramolecular hydrogen bonds, viz. O—H⋯N and N—H⋯O, involving the hydroxy substituent, the methoxy...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006725/ https://www.ncbi.nlm.nih.gov/pubmed/21587885 http://dx.doi.org/10.1107/S1600536810022002 |
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author | Liu, Shi-Yong You, Zhonglu |
author_facet | Liu, Shi-Yong You, Zhonglu |
author_sort | Liu, Shi-Yong |
collection | PubMed |
description | In the title compound, C(15)H(13)BrN(2)O(3), the molecule adopts an E configuration about the C=N bond and the two benzene rings form a dihedral angle of 20.3 (3)°. In the molecule, there are two intramolecular hydrogen bonds, viz. O—H⋯N and N—H⋯O, involving the hydroxy substituent, the methoxy O atom and the hydrazide NH group and N atom. In the crystal structure, molecules are linked through N—H⋯O hydrogen bonds, forming chains propagating along [010]. |
format | Text |
id | pubmed-3006725 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30067252010-12-30 (E)-N′-(5-Bromo-2-hydroxybenzylidene)-2-methoxybenzohydrazide Liu, Shi-Yong You, Zhonglu Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(13)BrN(2)O(3), the molecule adopts an E configuration about the C=N bond and the two benzene rings form a dihedral angle of 20.3 (3)°. In the molecule, there are two intramolecular hydrogen bonds, viz. O—H⋯N and N—H⋯O, involving the hydroxy substituent, the methoxy O atom and the hydrazide NH group and N atom. In the crystal structure, molecules are linked through N—H⋯O hydrogen bonds, forming chains propagating along [010]. International Union of Crystallography 2010-06-16 /pmc/articles/PMC3006725/ /pubmed/21587885 http://dx.doi.org/10.1107/S1600536810022002 Text en © Liu and You 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Liu, Shi-Yong You, Zhonglu (E)-N′-(5-Bromo-2-hydroxybenzylidene)-2-methoxybenzohydrazide |
title | (E)-N′-(5-Bromo-2-hydroxybenzylidene)-2-methoxybenzohydrazide |
title_full | (E)-N′-(5-Bromo-2-hydroxybenzylidene)-2-methoxybenzohydrazide |
title_fullStr | (E)-N′-(5-Bromo-2-hydroxybenzylidene)-2-methoxybenzohydrazide |
title_full_unstemmed | (E)-N′-(5-Bromo-2-hydroxybenzylidene)-2-methoxybenzohydrazide |
title_short | (E)-N′-(5-Bromo-2-hydroxybenzylidene)-2-methoxybenzohydrazide |
title_sort | (e)-n′-(5-bromo-2-hydroxybenzylidene)-2-methoxybenzohydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006725/ https://www.ncbi.nlm.nih.gov/pubmed/21587885 http://dx.doi.org/10.1107/S1600536810022002 |
work_keys_str_mv | AT liushiyong en5bromo2hydroxybenzylidene2methoxybenzohydrazide AT youzhonglu en5bromo2hydroxybenzylidene2methoxybenzohydrazide |