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Ethyl 1-(2-hydroxyethyl)-2-phenyl-1H-benzimidazole-5-carboxylate
There are two molecules in the asymmetric unit of the title compound, C(18)H(18)N(2)O(3). In each one, the benzimidazole ring system is essentially planar, with maximum deviations of 0.027 (1) and 0.032 (1)Å, and makes dihedral angles of 38.64 (6) and 41.48 (6)°, respectively, with the attached ben...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006730/ https://www.ncbi.nlm.nih.gov/pubmed/21588031 http://dx.doi.org/10.1107/S1600536810023639 |
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author | Hamzah, Nurasyikin Abd. Hamid, Shafida Abdul Rahim, Aisyah Saad Rosli, Mohd Mustaqim Fun, Hoong-Kun |
author_facet | Hamzah, Nurasyikin Abd. Hamid, Shafida Abdul Rahim, Aisyah Saad Rosli, Mohd Mustaqim Fun, Hoong-Kun |
author_sort | Hamzah, Nurasyikin |
collection | PubMed |
description | There are two molecules in the asymmetric unit of the title compound, C(18)H(18)N(2)O(3). In each one, the benzimidazole ring system is essentially planar, with maximum deviations of 0.027 (1) and 0.032 (1)Å, and makes dihedral angles of 38.64 (6) and 41.48 (6)°, respectively, with the attached benzene rings. An intramolecular C—H⋯O hydrogen bond is observed in each molecule. The two independent molecules are connected into a dimer by two intermolecular O—H⋯N hydrogen bonds. In the crystal, molecules form a two-dimensional layers parallel to (012) via weak intermolecular C—H⋯O hydrogen bonds. In addition, weak π-π stacking interactions are observed with centroid–centroid distances of 3.5244 (12) and 3.6189 (12) Å. |
format | Text |
id | pubmed-3006730 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30067302010-12-30 Ethyl 1-(2-hydroxyethyl)-2-phenyl-1H-benzimidazole-5-carboxylate Hamzah, Nurasyikin Abd. Hamid, Shafida Abdul Rahim, Aisyah Saad Rosli, Mohd Mustaqim Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers There are two molecules in the asymmetric unit of the title compound, C(18)H(18)N(2)O(3). In each one, the benzimidazole ring system is essentially planar, with maximum deviations of 0.027 (1) and 0.032 (1)Å, and makes dihedral angles of 38.64 (6) and 41.48 (6)°, respectively, with the attached benzene rings. An intramolecular C—H⋯O hydrogen bond is observed in each molecule. The two independent molecules are connected into a dimer by two intermolecular O—H⋯N hydrogen bonds. In the crystal, molecules form a two-dimensional layers parallel to (012) via weak intermolecular C—H⋯O hydrogen bonds. In addition, weak π-π stacking interactions are observed with centroid–centroid distances of 3.5244 (12) and 3.6189 (12) Å. International Union of Crystallography 2010-06-26 /pmc/articles/PMC3006730/ /pubmed/21588031 http://dx.doi.org/10.1107/S1600536810023639 Text en © Hamzah et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Hamzah, Nurasyikin Abd. Hamid, Shafida Abdul Rahim, Aisyah Saad Rosli, Mohd Mustaqim Fun, Hoong-Kun Ethyl 1-(2-hydroxyethyl)-2-phenyl-1H-benzimidazole-5-carboxylate |
title | Ethyl 1-(2-hydroxyethyl)-2-phenyl-1H-benzimidazole-5-carboxylate |
title_full | Ethyl 1-(2-hydroxyethyl)-2-phenyl-1H-benzimidazole-5-carboxylate |
title_fullStr | Ethyl 1-(2-hydroxyethyl)-2-phenyl-1H-benzimidazole-5-carboxylate |
title_full_unstemmed | Ethyl 1-(2-hydroxyethyl)-2-phenyl-1H-benzimidazole-5-carboxylate |
title_short | Ethyl 1-(2-hydroxyethyl)-2-phenyl-1H-benzimidazole-5-carboxylate |
title_sort | ethyl 1-(2-hydroxyethyl)-2-phenyl-1h-benzimidazole-5-carboxylate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006730/ https://www.ncbi.nlm.nih.gov/pubmed/21588031 http://dx.doi.org/10.1107/S1600536810023639 |
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