1-{6-Chloro-2-[(2-chloro-6-methyl­quinolin-3-yl)meth­oxy]-4-phenyl­quinolin-3-yl}ethanone

In the title compound, C(28)H(20)Cl(2)N(2)O(2), the 2-chloro­quinoline and 6-chloro­quinoline ring systems are twisted slightly, making a dihedral angle of 4.05 (3)°. The dihedral angle between the 2-quinoline ring system and the phenyl ring attached to it is 74.43 (5)°. In the crystal structure, a...

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Autores principales: Khan, F. Nawaz, Hathwar, Venkatesha R., Kumar, Rajesh, Kushwaha, Atul Kumar, Akkurt, Mehmet
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006731/
https://www.ncbi.nlm.nih.gov/pubmed/21587915
http://dx.doi.org/10.1107/S1600536810022701
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author Khan, F. Nawaz
Hathwar, Venkatesha R.
Kumar, Rajesh
Kushwaha, Atul Kumar
Akkurt, Mehmet
author_facet Khan, F. Nawaz
Hathwar, Venkatesha R.
Kumar, Rajesh
Kushwaha, Atul Kumar
Akkurt, Mehmet
author_sort Khan, F. Nawaz
collection PubMed
description In the title compound, C(28)H(20)Cl(2)N(2)O(2), the 2-chloro­quinoline and 6-chloro­quinoline ring systems are twisted slightly, making a dihedral angle of 4.05 (3)°. The dihedral angle between the 2-quinoline ring system and the phenyl ring attached to it is 74.43 (5)°. In the crystal structure, a pair of inter­molecular C—H⋯O hydrogen bonds connect the mol­ecules, forming centrosymmetric dimers with R (2) (2)(16) motifs. The dimers are further consolidated by a C—H⋯π inter­action and a π–π stacking inter­action with a centroid–centroid distance of 3.6562 (10) Å.
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spelling pubmed-30067312010-12-30 1-{6-Chloro-2-[(2-chloro-6-methyl­quinolin-3-yl)meth­oxy]-4-phenyl­quinolin-3-yl}ethanone Khan, F. Nawaz Hathwar, Venkatesha R. Kumar, Rajesh Kushwaha, Atul Kumar Akkurt, Mehmet Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(28)H(20)Cl(2)N(2)O(2), the 2-chloro­quinoline and 6-chloro­quinoline ring systems are twisted slightly, making a dihedral angle of 4.05 (3)°. The dihedral angle between the 2-quinoline ring system and the phenyl ring attached to it is 74.43 (5)°. In the crystal structure, a pair of inter­molecular C—H⋯O hydrogen bonds connect the mol­ecules, forming centrosymmetric dimers with R (2) (2)(16) motifs. The dimers are further consolidated by a C—H⋯π inter­action and a π–π stacking inter­action with a centroid–centroid distance of 3.6562 (10) Å. International Union of Crystallography 2010-06-18 /pmc/articles/PMC3006731/ /pubmed/21587915 http://dx.doi.org/10.1107/S1600536810022701 Text en © Khan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Khan, F. Nawaz
Hathwar, Venkatesha R.
Kumar, Rajesh
Kushwaha, Atul Kumar
Akkurt, Mehmet
1-{6-Chloro-2-[(2-chloro-6-methyl­quinolin-3-yl)meth­oxy]-4-phenyl­quinolin-3-yl}ethanone
title 1-{6-Chloro-2-[(2-chloro-6-methyl­quinolin-3-yl)meth­oxy]-4-phenyl­quinolin-3-yl}ethanone
title_full 1-{6-Chloro-2-[(2-chloro-6-methyl­quinolin-3-yl)meth­oxy]-4-phenyl­quinolin-3-yl}ethanone
title_fullStr 1-{6-Chloro-2-[(2-chloro-6-methyl­quinolin-3-yl)meth­oxy]-4-phenyl­quinolin-3-yl}ethanone
title_full_unstemmed 1-{6-Chloro-2-[(2-chloro-6-methyl­quinolin-3-yl)meth­oxy]-4-phenyl­quinolin-3-yl}ethanone
title_short 1-{6-Chloro-2-[(2-chloro-6-methyl­quinolin-3-yl)meth­oxy]-4-phenyl­quinolin-3-yl}ethanone
title_sort 1-{6-chloro-2-[(2-chloro-6-methyl­quinolin-3-yl)meth­oxy]-4-phenyl­quinolin-3-yl}ethanone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006731/
https://www.ncbi.nlm.nih.gov/pubmed/21587915
http://dx.doi.org/10.1107/S1600536810022701
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