2-Amino-5-methyl­pyridinium 4-carb­oxy­butano­ate

In the title salt, C(6)H(9)N(2) (+)·C(5)H(7)O(4) (−), the 2-amino-5-methyl­pyridinium cation is essentially planar, with a maximum deviation of 0.008 (1) Å. In the crystal, the protonated N atom and the 2-amino group are hydrogen bonded to the carboxyl­ate O atoms via a pair of N—H⋯O hydrogen bonds,...

Descripción completa

Detalles Bibliográficos
Autores principales: Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006734/
https://www.ncbi.nlm.nih.gov/pubmed/21588042
http://dx.doi.org/10.1107/S1600536810024451
_version_ 1782194209246150656
author Hemamalini, Madhukar
Fun, Hoong-Kun
author_facet Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Hemamalini, Madhukar
collection PubMed
description In the title salt, C(6)H(9)N(2) (+)·C(5)H(7)O(4) (−), the 2-amino-5-methyl­pyridinium cation is essentially planar, with a maximum deviation of 0.008 (1) Å. In the crystal, the protonated N atom and the 2-amino group are hydrogen bonded to the carboxyl­ate O atoms via a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The 4-carb­oxy­butano­ate anions are linked via O—H⋯O hydrogen bonds. The crystal structure is further stabilized by weak C—H⋯O inter­actions.
format Text
id pubmed-3006734
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30067342010-12-30 2-Amino-5-methyl­pyridinium 4-carb­oxy­butano­ate Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(6)H(9)N(2) (+)·C(5)H(7)O(4) (−), the 2-amino-5-methyl­pyridinium cation is essentially planar, with a maximum deviation of 0.008 (1) Å. In the crystal, the protonated N atom and the 2-amino group are hydrogen bonded to the carboxyl­ate O atoms via a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The 4-carb­oxy­butano­ate anions are linked via O—H⋯O hydrogen bonds. The crystal structure is further stabilized by weak C—H⋯O inter­actions. International Union of Crystallography 2010-06-26 /pmc/articles/PMC3006734/ /pubmed/21588042 http://dx.doi.org/10.1107/S1600536810024451 Text en © Hemamalini and Fun 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hemamalini, Madhukar
Fun, Hoong-Kun
2-Amino-5-methyl­pyridinium 4-carb­oxy­butano­ate
title 2-Amino-5-methyl­pyridinium 4-carb­oxy­butano­ate
title_full 2-Amino-5-methyl­pyridinium 4-carb­oxy­butano­ate
title_fullStr 2-Amino-5-methyl­pyridinium 4-carb­oxy­butano­ate
title_full_unstemmed 2-Amino-5-methyl­pyridinium 4-carb­oxy­butano­ate
title_short 2-Amino-5-methyl­pyridinium 4-carb­oxy­butano­ate
title_sort 2-amino-5-methyl­pyridinium 4-carb­oxy­butano­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006734/
https://www.ncbi.nlm.nih.gov/pubmed/21588042
http://dx.doi.org/10.1107/S1600536810024451
work_keys_str_mv AT hemamalinimadhukar 2amino5methylpyridinium4carboxybutanoate
AT funhoongkun 2amino5methylpyridinium4carboxybutanoate

Ejemplares similares