Poly[[bis­(μ-4,4′-bipyridyl-κ(2) N:N′)bis­(thio­cyanato-κN)manganese(II)] diethyl ether disolvate]

In the title compound, {[Mn(NCS)(2)(C(10)H(8)N(2))(2)]·2C(4)H(10)O}(n), the Mn(II) ion is coordinated by four N-bonded 4,4′-bipyridine (bipy) ligands and two N-bonded thio­cyanate anions in a distorted octa­hedral coordination geometry. The asymmetric unit consists of one Mn(II) ion and two bipy lig...

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Detalles Bibliográficos
Autores principales: Wriedt, Mario, Jess, Inke, Näther, Christian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006735/
https://www.ncbi.nlm.nih.gov/pubmed/21587708
http://dx.doi.org/10.1107/S1600536810021665
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author Wriedt, Mario
Jess, Inke
Näther, Christian
author_facet Wriedt, Mario
Jess, Inke
Näther, Christian
author_sort Wriedt, Mario
collection PubMed
description In the title compound, {[Mn(NCS)(2)(C(10)H(8)N(2))(2)]·2C(4)H(10)O}(n), the Mn(II) ion is coordinated by four N-bonded 4,4′-bipyridine (bipy) ligands and two N-bonded thio­cyanate anions in a distorted octa­hedral coordination geometry. The asymmetric unit consists of one Mn(II) ion and two bipy ligands each located on a twofold rotation axis, as well as one thio­cyanate anion and one diethyl ether mol­ecule in general positions. In the crystal structure, the metal centers with terminally bonded thicyanate anions are bridged by the bipy ligands into layers parallel to (001). The diethyl ether solvent mol­ecules occupy the voids of the structure.
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spelling pubmed-30067352010-12-30 Poly[[bis­(μ-4,4′-bipyridyl-κ(2) N:N′)bis­(thio­cyanato-κN)manganese(II)] diethyl ether disolvate] Wriedt, Mario Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Mn(NCS)(2)(C(10)H(8)N(2))(2)]·2C(4)H(10)O}(n), the Mn(II) ion is coordinated by four N-bonded 4,4′-bipyridine (bipy) ligands and two N-bonded thio­cyanate anions in a distorted octa­hedral coordination geometry. The asymmetric unit consists of one Mn(II) ion and two bipy ligands each located on a twofold rotation axis, as well as one thio­cyanate anion and one diethyl ether mol­ecule in general positions. In the crystal structure, the metal centers with terminally bonded thicyanate anions are bridged by the bipy ligands into layers parallel to (001). The diethyl ether solvent mol­ecules occupy the voids of the structure. International Union of Crystallography 2010-06-16 /pmc/articles/PMC3006735/ /pubmed/21587708 http://dx.doi.org/10.1107/S1600536810021665 Text en © Wriedt et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wriedt, Mario
Jess, Inke
Näther, Christian
Poly[[bis­(μ-4,4′-bipyridyl-κ(2) N:N′)bis­(thio­cyanato-κN)manganese(II)] diethyl ether disolvate]
title Poly[[bis­(μ-4,4′-bipyridyl-κ(2) N:N′)bis­(thio­cyanato-κN)manganese(II)] diethyl ether disolvate]
title_full Poly[[bis­(μ-4,4′-bipyridyl-κ(2) N:N′)bis­(thio­cyanato-κN)manganese(II)] diethyl ether disolvate]
title_fullStr Poly[[bis­(μ-4,4′-bipyridyl-κ(2) N:N′)bis­(thio­cyanato-κN)manganese(II)] diethyl ether disolvate]
title_full_unstemmed Poly[[bis­(μ-4,4′-bipyridyl-κ(2) N:N′)bis­(thio­cyanato-κN)manganese(II)] diethyl ether disolvate]
title_short Poly[[bis­(μ-4,4′-bipyridyl-κ(2) N:N′)bis­(thio­cyanato-κN)manganese(II)] diethyl ether disolvate]
title_sort poly[[bis­(μ-4,4′-bipyridyl-κ(2) n:n′)bis­(thio­cyanato-κn)manganese(ii)] diethyl ether disolvate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006735/
https://www.ncbi.nlm.nih.gov/pubmed/21587708
http://dx.doi.org/10.1107/S1600536810021665
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AT jessinke polybism44bipyridylk2nnbisthiocyanatoknmanganeseiidiethyletherdisolvate
AT natherchristian polybism44bipyridylk2nnbisthiocyanatoknmanganeseiidiethyletherdisolvate

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