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Di-μ-nicotinamide-κ(2) O:N (1);κ(2) N (1):O-bis­[aqua­bis­(4-meth­oxy­benzoato-κO)copper(II)]

The asymmetric unit of the centrosymmetric dinuclear title compound, [Cu(2)(C(8)H(7)O(3))(4)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], contains one half of the complex mol­ecule. Each Cu(II) atom is five-coordinated by one N atom from one bridging nicotinamide ligand and one O atom from another symmetry-related...

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Autores principales: Hökelek, Tuncer, Süzen, Yasemin, Tercan, Barış, Tenlik, Erdinç, Necefoğlu, Hacali
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006745/
https://www.ncbi.nlm.nih.gov/pubmed/21587726
http://dx.doi.org/10.1107/S1600536810022415
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author Hökelek, Tuncer
Süzen, Yasemin
Tercan, Barış
Tenlik, Erdinç
Necefoğlu, Hacali
author_facet Hökelek, Tuncer
Süzen, Yasemin
Tercan, Barış
Tenlik, Erdinç
Necefoğlu, Hacali
author_sort Hökelek, Tuncer
collection PubMed
description The asymmetric unit of the centrosymmetric dinuclear title compound, [Cu(2)(C(8)H(7)O(3))(4)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], contains one half of the complex mol­ecule. Each Cu(II) atom is five-coordinated by one N atom from one bridging nicotinamide ligand and one O atom from another symmetry-related bridging nicotinamide ligand, two O atoms from two 4-meth­oxy­benzoate ligands, and one water mol­ecule, forming a distorted square-pyramidal geometry. Inter­molecular O—H⋯O and N—H⋯O hydrogen bonds link the mol­ecules into layers parallel to ([Image: see text]01). π–π inter­actions, indicated by short inter­molecular distances of 3.801 (1) Å between the centroids of the benzene rings and 3.653 (1) Å between the centroids of the pyridine rings, further stabilize the structure.
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spelling pubmed-30067452010-12-30 Di-μ-nicotinamide-κ(2) O:N (1);κ(2) N (1):O-bis­[aqua­bis­(4-meth­oxy­benzoato-κO)copper(II)] Hökelek, Tuncer Süzen, Yasemin Tercan, Barış Tenlik, Erdinç Necefoğlu, Hacali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the centrosymmetric dinuclear title compound, [Cu(2)(C(8)H(7)O(3))(4)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], contains one half of the complex mol­ecule. Each Cu(II) atom is five-coordinated by one N atom from one bridging nicotinamide ligand and one O atom from another symmetry-related bridging nicotinamide ligand, two O atoms from two 4-meth­oxy­benzoate ligands, and one water mol­ecule, forming a distorted square-pyramidal geometry. Inter­molecular O—H⋯O and N—H⋯O hydrogen bonds link the mol­ecules into layers parallel to ([Image: see text]01). π–π inter­actions, indicated by short inter­molecular distances of 3.801 (1) Å between the centroids of the benzene rings and 3.653 (1) Å between the centroids of the pyridine rings, further stabilize the structure. International Union of Crystallography 2010-06-16 /pmc/articles/PMC3006745/ /pubmed/21587726 http://dx.doi.org/10.1107/S1600536810022415 Text en © Hökelek et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hökelek, Tuncer
Süzen, Yasemin
Tercan, Barış
Tenlik, Erdinç
Necefoğlu, Hacali
Di-μ-nicotinamide-κ(2) O:N (1);κ(2) N (1):O-bis­[aqua­bis­(4-meth­oxy­benzoato-κO)copper(II)]
title Di-μ-nicotinamide-κ(2) O:N (1);κ(2) N (1):O-bis­[aqua­bis­(4-meth­oxy­benzoato-κO)copper(II)]
title_full Di-μ-nicotinamide-κ(2) O:N (1);κ(2) N (1):O-bis­[aqua­bis­(4-meth­oxy­benzoato-κO)copper(II)]
title_fullStr Di-μ-nicotinamide-κ(2) O:N (1);κ(2) N (1):O-bis­[aqua­bis­(4-meth­oxy­benzoato-κO)copper(II)]
title_full_unstemmed Di-μ-nicotinamide-κ(2) O:N (1);κ(2) N (1):O-bis­[aqua­bis­(4-meth­oxy­benzoato-κO)copper(II)]
title_short Di-μ-nicotinamide-κ(2) O:N (1);κ(2) N (1):O-bis­[aqua­bis­(4-meth­oxy­benzoato-κO)copper(II)]
title_sort di-μ-nicotinamide-κ(2) o:n (1);κ(2) n (1):o-bis­[aqua­bis­(4-meth­oxy­benzoato-κo)copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006745/
https://www.ncbi.nlm.nih.gov/pubmed/21587726
http://dx.doi.org/10.1107/S1600536810022415
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