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Di-μ-nicotinamide-κ(2) O:N (1);κ(2) N (1):O-bis[aquabis(4-methoxybenzoato-κO)copper(II)]
The asymmetric unit of the centrosymmetric dinuclear title compound, [Cu(2)(C(8)H(7)O(3))(4)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], contains one half of the complex molecule. Each Cu(II) atom is five-coordinated by one N atom from one bridging nicotinamide ligand and one O atom from another symmetry-related...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006745/ https://www.ncbi.nlm.nih.gov/pubmed/21587726 http://dx.doi.org/10.1107/S1600536810022415 |
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author | Hökelek, Tuncer Süzen, Yasemin Tercan, Barış Tenlik, Erdinç Necefoğlu, Hacali |
author_facet | Hökelek, Tuncer Süzen, Yasemin Tercan, Barış Tenlik, Erdinç Necefoğlu, Hacali |
author_sort | Hökelek, Tuncer |
collection | PubMed |
description | The asymmetric unit of the centrosymmetric dinuclear title compound, [Cu(2)(C(8)H(7)O(3))(4)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], contains one half of the complex molecule. Each Cu(II) atom is five-coordinated by one N atom from one bridging nicotinamide ligand and one O atom from another symmetry-related bridging nicotinamide ligand, two O atoms from two 4-methoxybenzoate ligands, and one water molecule, forming a distorted square-pyramidal geometry. Intermolecular O—H⋯O and N—H⋯O hydrogen bonds link the molecules into layers parallel to ([Image: see text]01). π–π interactions, indicated by short intermolecular distances of 3.801 (1) Å between the centroids of the benzene rings and 3.653 (1) Å between the centroids of the pyridine rings, further stabilize the structure. |
format | Text |
id | pubmed-3006745 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30067452010-12-30 Di-μ-nicotinamide-κ(2) O:N (1);κ(2) N (1):O-bis[aquabis(4-methoxybenzoato-κO)copper(II)] Hökelek, Tuncer Süzen, Yasemin Tercan, Barış Tenlik, Erdinç Necefoğlu, Hacali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the centrosymmetric dinuclear title compound, [Cu(2)(C(8)H(7)O(3))(4)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], contains one half of the complex molecule. Each Cu(II) atom is five-coordinated by one N atom from one bridging nicotinamide ligand and one O atom from another symmetry-related bridging nicotinamide ligand, two O atoms from two 4-methoxybenzoate ligands, and one water molecule, forming a distorted square-pyramidal geometry. Intermolecular O—H⋯O and N—H⋯O hydrogen bonds link the molecules into layers parallel to ([Image: see text]01). π–π interactions, indicated by short intermolecular distances of 3.801 (1) Å between the centroids of the benzene rings and 3.653 (1) Å between the centroids of the pyridine rings, further stabilize the structure. International Union of Crystallography 2010-06-16 /pmc/articles/PMC3006745/ /pubmed/21587726 http://dx.doi.org/10.1107/S1600536810022415 Text en © Hökelek et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Hökelek, Tuncer Süzen, Yasemin Tercan, Barış Tenlik, Erdinç Necefoğlu, Hacali Di-μ-nicotinamide-κ(2) O:N (1);κ(2) N (1):O-bis[aquabis(4-methoxybenzoato-κO)copper(II)] |
title | Di-μ-nicotinamide-κ(2)
O:N
(1);κ(2)
N
(1):O-bis[aquabis(4-methoxybenzoato-κO)copper(II)] |
title_full | Di-μ-nicotinamide-κ(2)
O:N
(1);κ(2)
N
(1):O-bis[aquabis(4-methoxybenzoato-κO)copper(II)] |
title_fullStr | Di-μ-nicotinamide-κ(2)
O:N
(1);κ(2)
N
(1):O-bis[aquabis(4-methoxybenzoato-κO)copper(II)] |
title_full_unstemmed | Di-μ-nicotinamide-κ(2)
O:N
(1);κ(2)
N
(1):O-bis[aquabis(4-methoxybenzoato-κO)copper(II)] |
title_short | Di-μ-nicotinamide-κ(2)
O:N
(1);κ(2)
N
(1):O-bis[aquabis(4-methoxybenzoato-κO)copper(II)] |
title_sort | di-μ-nicotinamide-κ(2)
o:n
(1);κ(2)
n
(1):o-bis[aquabis(4-methoxybenzoato-κo)copper(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006745/ https://www.ncbi.nlm.nih.gov/pubmed/21587726 http://dx.doi.org/10.1107/S1600536810022415 |
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