3-Hy­droxy-8-oxo-3-nor-methyl­chamigrane-2,7-peroxide

In the title compound, C(14)H(22)O(4) (systematic name: 9-hy­droxy-1,5,5-trimethyl-1,8-epidi­oxy­spiro­[5.5]decan-2-one), which was isolated from the fermentation broth of Steccherinum ochraceum, the two six-membered rings adopt chair conformations and are bridged by a peroxide group. The hy­droxy H...

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Detalles Bibliográficos
Autor principal: Liu, Dongze
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006748/
https://www.ncbi.nlm.nih.gov/pubmed/21588070
http://dx.doi.org/10.1107/S1600536810024517
Descripción
Sumario:In the title compound, C(14)H(22)O(4) (systematic name: 9-hy­droxy-1,5,5-trimethyl-1,8-epidi­oxy­spiro­[5.5]decan-2-one), which was isolated from the fermentation broth of Steccherinum ochraceum, the two six-membered rings adopt chair conformations and are bridged by a peroxide group. The hy­droxy H atom forms a three-centre cyclic inter­molecular O—H⋯(O,O′) hydrogen-bonding inter­action with a peroxide and a carbonyl O-atom acceptor, forming [100] chains.

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