3-Hy­droxy-8-oxo-3-nor-methyl­chamigrane-2,7-peroxide

In the title compound, C(14)H(22)O(4) (systematic name: 9-hy­droxy-1,5,5-trimethyl-1,8-epidi­oxy­spiro­[5.5]decan-2-one), which was isolated from the fermentation broth of Steccherinum ochraceum, the two six-membered rings adopt chair conformations and are bridged by a peroxide group. The hy­droxy H...

Descripción completa

Detalles Bibliográficos
Autor principal: Liu, Dongze
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006748/
https://www.ncbi.nlm.nih.gov/pubmed/21588070
http://dx.doi.org/10.1107/S1600536810024517
_version_ 1782194212572233728
author Liu, Dongze
author_facet Liu, Dongze
author_sort Liu, Dongze
collection PubMed
description In the title compound, C(14)H(22)O(4) (systematic name: 9-hy­droxy-1,5,5-trimethyl-1,8-epidi­oxy­spiro­[5.5]decan-2-one), which was isolated from the fermentation broth of Steccherinum ochraceum, the two six-membered rings adopt chair conformations and are bridged by a peroxide group. The hy­droxy H atom forms a three-centre cyclic inter­molecular O—H⋯(O,O′) hydrogen-bonding inter­action with a peroxide and a carbonyl O-atom acceptor, forming [100] chains.
format Text
id pubmed-3006748
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30067482010-12-30 3-Hy­droxy-8-oxo-3-nor-methyl­chamigrane-2,7-peroxide Liu, Dongze Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(22)O(4) (systematic name: 9-hy­droxy-1,5,5-trimethyl-1,8-epidi­oxy­spiro­[5.5]decan-2-one), which was isolated from the fermentation broth of Steccherinum ochraceum, the two six-membered rings adopt chair conformations and are bridged by a peroxide group. The hy­droxy H atom forms a three-centre cyclic inter­molecular O—H⋯(O,O′) hydrogen-bonding inter­action with a peroxide and a carbonyl O-atom acceptor, forming [100] chains. International Union of Crystallography 2010-06-30 /pmc/articles/PMC3006748/ /pubmed/21588070 http://dx.doi.org/10.1107/S1600536810024517 Text en © Dongze Liu 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liu, Dongze
3-Hy­droxy-8-oxo-3-nor-methyl­chamigrane-2,7-peroxide
title 3-Hy­droxy-8-oxo-3-nor-methyl­chamigrane-2,7-peroxide
title_full 3-Hy­droxy-8-oxo-3-nor-methyl­chamigrane-2,7-peroxide
title_fullStr 3-Hy­droxy-8-oxo-3-nor-methyl­chamigrane-2,7-peroxide
title_full_unstemmed 3-Hy­droxy-8-oxo-3-nor-methyl­chamigrane-2,7-peroxide
title_short 3-Hy­droxy-8-oxo-3-nor-methyl­chamigrane-2,7-peroxide
title_sort 3-hy­droxy-8-oxo-3-nor-methyl­chamigrane-2,7-peroxide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006748/
https://www.ncbi.nlm.nih.gov/pubmed/21588070
http://dx.doi.org/10.1107/S1600536810024517
work_keys_str_mv AT liudongze 3hydroxy8oxo3normethylchamigrane27peroxide

Ejemplares similares