Triethyl­ammonium 1,1′-binaphthyl-2,2′-diyl phosphate

In the crystal structure of the title compound, C(6)H(16)N(+)·C(20)H(12)O(4)P(−), an N—H⋯O inter­action links the cation to the anion. The N atom in the triethyl­ammonium cation exhibits a trigonal-bipyramidal coordination geometry and forms an N—H⋯O inter­action with one phosphate O atom of the 1,1...

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Detalles Bibliográficos
Autores principales: Gowda, Ravikumar R., Ramkumar, Venkatachalam, Chakraborty, Debashis
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006757/
https://www.ncbi.nlm.nih.gov/pubmed/21587856
http://dx.doi.org/10.1107/S160053681002026X
Descripción
Sumario:In the crystal structure of the title compound, C(6)H(16)N(+)·C(20)H(12)O(4)P(−), an N—H⋯O inter­action links the cation to the anion. The N atom in the triethyl­ammonium cation exhibits a trigonal-bipyramidal coordination geometry and forms an N—H⋯O inter­action with one phosphate O atom of the 1,1′-binaphthyl-2,2′-diyl phosphate ligand. A bifurcated C—H⋯O inter­action with the other phosphate O atom links molecules along the a axis. The dihedral angle between the two naphthyl ring systems is 58.92 (3)°. The refined Flack parameter value of 0.50 (10) indicates inversion twinning.

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