Triethyl­ammonium 1,1′-binaphthyl-2,2′-diyl phosphate

In the crystal structure of the title compound, C(6)H(16)N(+)·C(20)H(12)O(4)P(−), an N—H⋯O inter­action links the cation to the anion. The N atom in the triethyl­ammonium cation exhibits a trigonal-bipyramidal coordination geometry and forms an N—H⋯O inter­action with one phosphate O atom of the 1,1...

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Detalles Bibliográficos
Autores principales: Gowda, Ravikumar R., Ramkumar, Venkatachalam, Chakraborty, Debashis
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006757/
https://www.ncbi.nlm.nih.gov/pubmed/21587856
http://dx.doi.org/10.1107/S160053681002026X
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author Gowda, Ravikumar R.
Ramkumar, Venkatachalam
Chakraborty, Debashis
author_facet Gowda, Ravikumar R.
Ramkumar, Venkatachalam
Chakraborty, Debashis
author_sort Gowda, Ravikumar R.
collection PubMed
description In the crystal structure of the title compound, C(6)H(16)N(+)·C(20)H(12)O(4)P(−), an N—H⋯O inter­action links the cation to the anion. The N atom in the triethyl­ammonium cation exhibits a trigonal-bipyramidal coordination geometry and forms an N—H⋯O inter­action with one phosphate O atom of the 1,1′-binaphthyl-2,2′-diyl phosphate ligand. A bifurcated C—H⋯O inter­action with the other phosphate O atom links molecules along the a axis. The dihedral angle between the two naphthyl ring systems is 58.92 (3)°. The refined Flack parameter value of 0.50 (10) indicates inversion twinning.
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spelling pubmed-30067572010-12-30 Triethyl­ammonium 1,1′-binaphthyl-2,2′-diyl phosphate Gowda, Ravikumar R. Ramkumar, Venkatachalam Chakraborty, Debashis Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(6)H(16)N(+)·C(20)H(12)O(4)P(−), an N—H⋯O inter­action links the cation to the anion. The N atom in the triethyl­ammonium cation exhibits a trigonal-bipyramidal coordination geometry and forms an N—H⋯O inter­action with one phosphate O atom of the 1,1′-binaphthyl-2,2′-diyl phosphate ligand. A bifurcated C—H⋯O inter­action with the other phosphate O atom links molecules along the a axis. The dihedral angle between the two naphthyl ring systems is 58.92 (3)°. The refined Flack parameter value of 0.50 (10) indicates inversion twinning. International Union of Crystallography 2010-06-16 /pmc/articles/PMC3006757/ /pubmed/21587856 http://dx.doi.org/10.1107/S160053681002026X Text en © Gowda et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gowda, Ravikumar R.
Ramkumar, Venkatachalam
Chakraborty, Debashis
Triethyl­ammonium 1,1′-binaphthyl-2,2′-diyl phosphate
title Triethyl­ammonium 1,1′-binaphthyl-2,2′-diyl phosphate
title_full Triethyl­ammonium 1,1′-binaphthyl-2,2′-diyl phosphate
title_fullStr Triethyl­ammonium 1,1′-binaphthyl-2,2′-diyl phosphate
title_full_unstemmed Triethyl­ammonium 1,1′-binaphthyl-2,2′-diyl phosphate
title_short Triethyl­ammonium 1,1′-binaphthyl-2,2′-diyl phosphate
title_sort triethyl­ammonium 1,1′-binaphthyl-2,2′-diyl phosphate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006757/
https://www.ncbi.nlm.nih.gov/pubmed/21587856
http://dx.doi.org/10.1107/S160053681002026X
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AT ramkumarvenkatachalam triethylammonium11binaphthyl22diylphosphate
AT chakrabortydebashis triethylammonium11binaphthyl22diylphosphate

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