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Chlorido(2,3,7,8,12,13,17,18-octaethylporphyrinato)iron(III) dichloromethane sesquisolvate
The title molecule, [Fe(C(36)H(44)N(4))Cl]·1.5CH(2)Cl(2), is a high-spin square-pyramidal iron(III) porphyrinate with an average value for the equatorial Fe—N bond lengths of 2.065 (3) Å and an axial Fe—Cl distance of 2.2430 (13) Å. The iron cation is displaced by 0.518 (1) Å from the 24-atom mean...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006760/ https://www.ncbi.nlm.nih.gov/pubmed/21587675 http://dx.doi.org/10.1107/S1600536810020015 |
| _version_ | 1782194215507197952 |
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| author | Safo, Martin K. Buentello, Kristin E. Oliver, Allen G. Scheidt, W. Robert |
| author_facet | Safo, Martin K. Buentello, Kristin E. Oliver, Allen G. Scheidt, W. Robert |
| author_sort | Safo, Martin K. |
| collection | PubMed |
| description | The title molecule, [Fe(C(36)H(44)N(4))Cl]·1.5CH(2)Cl(2), is a high-spin square-pyramidal iron(III) porphyrinate with an average value for the equatorial Fe—N bond lengths of 2.065 (3) Å and an axial Fe—Cl distance of 2.2430 (13) Å. The iron cation is displaced by 0.518 (1) Å from the 24-atom mean plane of the porphyrin ring. These values are typical for high-spin iron(III) porphyrinates. |
| format | Text |
| id | pubmed-3006760 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30067602010-12-30 Chlorido(2,3,7,8,12,13,17,18-octaethylporphyrinato)iron(III) dichloromethane sesquisolvate Safo, Martin K. Buentello, Kristin E. Oliver, Allen G. Scheidt, W. Robert Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title molecule, [Fe(C(36)H(44)N(4))Cl]·1.5CH(2)Cl(2), is a high-spin square-pyramidal iron(III) porphyrinate with an average value for the equatorial Fe—N bond lengths of 2.065 (3) Å and an axial Fe—Cl distance of 2.2430 (13) Å. The iron cation is displaced by 0.518 (1) Å from the 24-atom mean plane of the porphyrin ring. These values are typical for high-spin iron(III) porphyrinates. International Union of Crystallography 2010-06-05 /pmc/articles/PMC3006760/ /pubmed/21587675 http://dx.doi.org/10.1107/S1600536810020015 Text en © Safo et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Safo, Martin K. Buentello, Kristin E. Oliver, Allen G. Scheidt, W. Robert Chlorido(2,3,7,8,12,13,17,18-octaethylporphyrinato)iron(III) dichloromethane sesquisolvate |
| title | Chlorido(2,3,7,8,12,13,17,18-octaethylporphyrinato)iron(III) dichloromethane sesquisolvate |
| title_full | Chlorido(2,3,7,8,12,13,17,18-octaethylporphyrinato)iron(III) dichloromethane sesquisolvate |
| title_fullStr | Chlorido(2,3,7,8,12,13,17,18-octaethylporphyrinato)iron(III) dichloromethane sesquisolvate |
| title_full_unstemmed | Chlorido(2,3,7,8,12,13,17,18-octaethylporphyrinato)iron(III) dichloromethane sesquisolvate |
| title_short | Chlorido(2,3,7,8,12,13,17,18-octaethylporphyrinato)iron(III) dichloromethane sesquisolvate |
| title_sort | chlorido(2,3,7,8,12,13,17,18-octaethylporphyrinato)iron(iii) dichloromethane sesquisolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006760/ https://www.ncbi.nlm.nih.gov/pubmed/21587675 http://dx.doi.org/10.1107/S1600536810020015 |
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