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(μ-Oxalato-κ(4) O (1),O (2):O (1′),O (2′))bis­[bis­(2,2′-bipyridine-κ(2) N,N′)cobalt(II)] μ(6)-oxido-dodeca-μ(2)-oxido-hexa­oxido-hexa­tungstate(VI)

The asymmetric unit of the title compound, [Co(2)(C(2)O(4))(C(10)H(8)N(2))(4)][W(6)O(19)], consists of one half of the complex [Co(2)(C(2)O(4))(C(10)H(8)N(2))(4)](2+) cation and one half of the Lindqvist-type [W(6)O(19)](2−) isopolyanion. Both constituents are completed by crystallographic inversion...

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Detalles Bibliográficos
Autores principales: Shi, Congwen, Fan, Liming, Wei, Peihai, Li, Bin, Zhang, Xiutang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006761/
https://www.ncbi.nlm.nih.gov/pubmed/21587738
http://dx.doi.org/10.1107/S1600536810023007
Descripción
Sumario:The asymmetric unit of the title compound, [Co(2)(C(2)O(4))(C(10)H(8)N(2))(4)][W(6)O(19)], consists of one half of the complex [Co(2)(C(2)O(4))(C(10)H(8)N(2))(4)](2+) cation and one half of the Lindqvist-type [W(6)O(19)](2−) isopolyanion. Both constituents are completed by crystallographic inversion symmetry. In the dimeric cation, the Co(II) atom is surrounded in a distorted octa­hedral coordination by four N atoms from two chelating 2,2′-bipyridine ligands and by two O atoms from the chelating oxalate anion. The Lindqvist-type anion exhibits the characteristic W—O bond-length distribution, with the shortest bonds being the W—O(terminal) bonds and the longest being those to the central O atom.