4-Chloro-N-(3-chloro­phen­yl)-2-methyl­benzene­sulfonamide

In the title compound, C(13)H(11)Cl(2)NO(2)S, the conformation of the N—H bond in the C—SO(2)—NH—C segment is anti to the meta-Cl atom on the aniline ring and syn to the ortho-methyl group on the sulfonyl­benzene ring. Furthermore, the torsion angle of the C—SO(2)—NH—C segment in the mol­ecule is 80...

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Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Foro, Sabine, Nirmala, P. G., Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006774/
https://www.ncbi.nlm.nih.gov/pubmed/21587922
http://dx.doi.org/10.1107/S1600536810022968
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author Gowda, B. Thimme
Foro, Sabine
Nirmala, P. G.
Fuess, Hartmut
author_facet Gowda, B. Thimme
Foro, Sabine
Nirmala, P. G.
Fuess, Hartmut
author_sort Gowda, B. Thimme
collection PubMed
description In the title compound, C(13)H(11)Cl(2)NO(2)S, the conformation of the N—H bond in the C—SO(2)—NH—C segment is anti to the meta-Cl atom on the aniline ring and syn to the ortho-methyl group on the sulfonyl­benzene ring. Furthermore, the torsion angle of the C—SO(2)—NH—C segment in the mol­ecule is 80.1 (3)°. The two benzene rings are tilted relative to each other by 70.9 (1)°. In the crystal, pairs of inter­molecular N—H⋯O hydrogen bonds link the mol­ecules via inversion-related dimers into infinite column-like chains.
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spelling pubmed-30067742010-12-30 4-Chloro-N-(3-chloro­phen­yl)-2-methyl­benzene­sulfonamide Gowda, B. Thimme Foro, Sabine Nirmala, P. G. Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(11)Cl(2)NO(2)S, the conformation of the N—H bond in the C—SO(2)—NH—C segment is anti to the meta-Cl atom on the aniline ring and syn to the ortho-methyl group on the sulfonyl­benzene ring. Furthermore, the torsion angle of the C—SO(2)—NH—C segment in the mol­ecule is 80.1 (3)°. The two benzene rings are tilted relative to each other by 70.9 (1)°. In the crystal, pairs of inter­molecular N—H⋯O hydrogen bonds link the mol­ecules via inversion-related dimers into infinite column-like chains. International Union of Crystallography 2010-06-18 /pmc/articles/PMC3006774/ /pubmed/21587922 http://dx.doi.org/10.1107/S1600536810022968 Text en © Gowda et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gowda, B. Thimme
Foro, Sabine
Nirmala, P. G.
Fuess, Hartmut
4-Chloro-N-(3-chloro­phen­yl)-2-methyl­benzene­sulfonamide
title 4-Chloro-N-(3-chloro­phen­yl)-2-methyl­benzene­sulfonamide
title_full 4-Chloro-N-(3-chloro­phen­yl)-2-methyl­benzene­sulfonamide
title_fullStr 4-Chloro-N-(3-chloro­phen­yl)-2-methyl­benzene­sulfonamide
title_full_unstemmed 4-Chloro-N-(3-chloro­phen­yl)-2-methyl­benzene­sulfonamide
title_short 4-Chloro-N-(3-chloro­phen­yl)-2-methyl­benzene­sulfonamide
title_sort 4-chloro-n-(3-chloro­phen­yl)-2-methyl­benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006774/
https://www.ncbi.nlm.nih.gov/pubmed/21587922
http://dx.doi.org/10.1107/S1600536810022968
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AT fuesshartmut 4chloron3chlorophenyl2methylbenzenesulfonamide

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