Trichloridobis(ethyl­diphenyl­phosphine)(tetra­hydro­furan)­molybdenum(III)

In the mononuclear title compound, [MoCl(3)(C(4)H(8)O)(C(14)H(15)P)(2)], obtained by the reaction of trichloro­tris­(tetra­hydro­furan)­molybdenum(III) and ethyl­diphenyl­phosphine in tetra­hydro­furan (THF) solution, the Mo(III) atom is six-coordinated by one O atom of a THF mol­ecule, two P atoms...

Descripción completa

Detalles Bibliográficos
Autores principales: Kruczyński, Tomasz, Pikies, Jerzy, Ponikiewski, Łukasz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006780/
https://www.ncbi.nlm.nih.gov/pubmed/21587711
http://dx.doi.org/10.1107/S1600536810021690
_version_ 1782194220309676032
author Kruczyński, Tomasz
Pikies, Jerzy
Ponikiewski, Łukasz
author_facet Kruczyński, Tomasz
Pikies, Jerzy
Ponikiewski, Łukasz
author_sort Kruczyński, Tomasz
collection PubMed
description In the mononuclear title compound, [MoCl(3)(C(4)H(8)O)(C(14)H(15)P)(2)], obtained by the reaction of trichloro­tris­(tetra­hydro­furan)­molybdenum(III) and ethyl­diphenyl­phosphine in tetra­hydro­furan (THF) solution, the Mo(III) atom is six-coordinated by one O atom of a THF mol­ecule, two P atoms from two ethyl­diphenyl­phosphine ligands and three Cl atoms in a distorted octa­hedral geometry. The C atoms of the THF molecule are disordered over two positions in a 0.55 (2):0.45 (2) ratio.
format Text
id pubmed-3006780
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30067802010-12-30 Trichloridobis(ethyl­diphenyl­phosphine)(tetra­hydro­furan)­molybdenum(III) Kruczyński, Tomasz Pikies, Jerzy Ponikiewski, Łukasz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title compound, [MoCl(3)(C(4)H(8)O)(C(14)H(15)P)(2)], obtained by the reaction of trichloro­tris­(tetra­hydro­furan)­molybdenum(III) and ethyl­diphenyl­phosphine in tetra­hydro­furan (THF) solution, the Mo(III) atom is six-coordinated by one O atom of a THF mol­ecule, two P atoms from two ethyl­diphenyl­phosphine ligands and three Cl atoms in a distorted octa­hedral geometry. The C atoms of the THF molecule are disordered over two positions in a 0.55 (2):0.45 (2) ratio. International Union of Crystallography 2010-06-16 /pmc/articles/PMC3006780/ /pubmed/21587711 http://dx.doi.org/10.1107/S1600536810021690 Text en © Kruczyński et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kruczyński, Tomasz
Pikies, Jerzy
Ponikiewski, Łukasz
Trichloridobis(ethyl­diphenyl­phosphine)(tetra­hydro­furan)­molybdenum(III)
title Trichloridobis(ethyl­diphenyl­phosphine)(tetra­hydro­furan)­molybdenum(III)
title_full Trichloridobis(ethyl­diphenyl­phosphine)(tetra­hydro­furan)­molybdenum(III)
title_fullStr Trichloridobis(ethyl­diphenyl­phosphine)(tetra­hydro­furan)­molybdenum(III)
title_full_unstemmed Trichloridobis(ethyl­diphenyl­phosphine)(tetra­hydro­furan)­molybdenum(III)
title_short Trichloridobis(ethyl­diphenyl­phosphine)(tetra­hydro­furan)­molybdenum(III)
title_sort trichloridobis(ethyl­diphenyl­phosphine)(tetra­hydro­furan)­molybdenum(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006780/
https://www.ncbi.nlm.nih.gov/pubmed/21587711
http://dx.doi.org/10.1107/S1600536810021690
work_keys_str_mv AT kruczynskitomasz trichloridobisethyldiphenylphosphinetetrahydrofuranmolybdenumiii
AT pikiesjerzy trichloridobisethyldiphenylphosphinetetrahydrofuranmolybdenumiii
AT ponikiewskiłukasz trichloridobisethyldiphenylphosphinetetrahydrofuranmolybdenumiii

Ejemplares similares