Methyl 4-methyl­sulfonyl-2-nitro­benzoate

The title compound, C(9)H(9)NO(6)S, was prepared by the reaction of methanol and thionyl chloride with 4-methyl­sulfonyl-2-nitro­benzoic acid under mild conditions. The dihedral angle between the nitro group and benzene ring is 21.33 (19)° and that between the carboxyl­ate group and the benzene ring...

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Detalles Bibliográficos
Autores principales: Hou, Yan-Jun, Chu, Wen-Yi, Sui, Jun, Sun, Zhi-Zhong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006783/
https://www.ncbi.nlm.nih.gov/pubmed/21587895
http://dx.doi.org/10.1107/S1600536810021914
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author Hou, Yan-Jun
Chu, Wen-Yi
Sui, Jun
Sun, Zhi-Zhong
author_facet Hou, Yan-Jun
Chu, Wen-Yi
Sui, Jun
Sun, Zhi-Zhong
author_sort Hou, Yan-Jun
collection PubMed
description The title compound, C(9)H(9)NO(6)S, was prepared by the reaction of methanol and thionyl chloride with 4-methyl­sulfonyl-2-nitro­benzoic acid under mild conditions. The dihedral angle between the nitro group and benzene ring is 21.33 (19)° and that between the carboxyl­ate group and the benzene ring is 72.09 (17)°. The crystal structure is stabilized by weak inter­molecular bifurcated C—H⋯O inter­actions occurring in the (100) plane.
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spelling pubmed-30067832010-12-30 Methyl 4-methyl­sulfonyl-2-nitro­benzoate Hou, Yan-Jun Chu, Wen-Yi Sui, Jun Sun, Zhi-Zhong Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(9)H(9)NO(6)S, was prepared by the reaction of methanol and thionyl chloride with 4-methyl­sulfonyl-2-nitro­benzoic acid under mild conditions. The dihedral angle between the nitro group and benzene ring is 21.33 (19)° and that between the carboxyl­ate group and the benzene ring is 72.09 (17)°. The crystal structure is stabilized by weak inter­molecular bifurcated C—H⋯O inter­actions occurring in the (100) plane. International Union of Crystallography 2010-06-16 /pmc/articles/PMC3006783/ /pubmed/21587895 http://dx.doi.org/10.1107/S1600536810021914 Text en © Hou et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hou, Yan-Jun
Chu, Wen-Yi
Sui, Jun
Sun, Zhi-Zhong
Methyl 4-methyl­sulfonyl-2-nitro­benzoate
title Methyl 4-methyl­sulfonyl-2-nitro­benzoate
title_full Methyl 4-methyl­sulfonyl-2-nitro­benzoate
title_fullStr Methyl 4-methyl­sulfonyl-2-nitro­benzoate
title_full_unstemmed Methyl 4-methyl­sulfonyl-2-nitro­benzoate
title_short Methyl 4-methyl­sulfonyl-2-nitro­benzoate
title_sort methyl 4-methyl­sulfonyl-2-nitro­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006783/
https://www.ncbi.nlm.nih.gov/pubmed/21587895
http://dx.doi.org/10.1107/S1600536810021914
work_keys_str_mv AT houyanjun methyl4methylsulfonyl2nitrobenzoate
AT chuwenyi methyl4methylsulfonyl2nitrobenzoate
AT suijun methyl4methylsulfonyl2nitrobenzoate
AT sunzhizhong methyl4methylsulfonyl2nitrobenzoate

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