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catena-Poly[[bis(μ-3-aminopyrazine-2-carboxylato)-κ(3) N (1),O:O;κ(3) O:N (1),O)dilithium]-di-μ-aqua]
The title compound, [Li(C(5)H(4)N(3)O(2))(H(2)O)](n), is composed of centrosymmetric dinuclear units, in which the Li(I) ions are bridged by two carboxylate O atoms donated by two ligands. The dinuclear unit is nearly planar [r.m.s. deviation = 0.0125 (2) Å]. The Li(I) ion is coordinated by an N,O-...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006785/ https://www.ncbi.nlm.nih.gov/pubmed/21587683 http://dx.doi.org/10.1107/S1600536810020647 |
Sumario: | The title compound, [Li(C(5)H(4)N(3)O(2))(H(2)O)](n), is composed of centrosymmetric dinuclear units, in which the Li(I) ions are bridged by two carboxylate O atoms donated by two ligands. The dinuclear unit is nearly planar [r.m.s. deviation = 0.0125 (2) Å]. The Li(I) ion is coordinated by an N,O-chelating ligand, a bridging carboxylate O atom from another ligand and two bridging water O atoms in a distorted trigonal-bipyramidal geometry. The water O atoms bridge the dinuclear units into a polymeric molecular column along [010]. The columns are held together by O—H⋯O and N—H⋯N hydrogen bonds. An intramolecular N—H⋯O interaction also occurs. |
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