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catena-Poly[[bis­(μ-3-amino­pyrazine-2-carboxyl­ato)-κ(3) N (1),O:O;κ(3) O:N (1),O)dilithium]-di-μ-aqua]

The title compound, [Li(C(5)H(4)N(3)O(2))(H(2)O)](n), is composed of centrosymmetric dinuclear units, in which the Li(I) ions are bridged by two carboxyl­ate O atoms donated by two ligands. The dinuclear unit is nearly planar [r.m.s. deviation = 0.0125 (2) Å]. The Li(I) ion is coordinated by an N,O-...

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Detalles Bibliográficos
Autores principales: Starosta, Wojciech, Leciejewicz, Janusz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006785/
https://www.ncbi.nlm.nih.gov/pubmed/21587683
http://dx.doi.org/10.1107/S1600536810020647
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author Starosta, Wojciech
Leciejewicz, Janusz
author_facet Starosta, Wojciech
Leciejewicz, Janusz
author_sort Starosta, Wojciech
collection PubMed
description The title compound, [Li(C(5)H(4)N(3)O(2))(H(2)O)](n), is composed of centrosymmetric dinuclear units, in which the Li(I) ions are bridged by two carboxyl­ate O atoms donated by two ligands. The dinuclear unit is nearly planar [r.m.s. deviation = 0.0125 (2) Å]. The Li(I) ion is coordinated by an N,O-chelating ligand, a bridging carboxyl­ate O atom from another ligand and two bridging water O atoms in a distorted trigonal-bipyra­midal geometry. The water O atoms bridge the dinuclear units into a polymeric mol­ecular column along [010]. The columns are held together by O—H⋯O and N—H⋯N hydrogen bonds. An intra­molecular N—H⋯O inter­action also occurs.
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spelling pubmed-30067852010-12-30 catena-Poly[[bis­(μ-3-amino­pyrazine-2-carboxyl­ato)-κ(3) N (1),O:O;κ(3) O:N (1),O)dilithium]-di-μ-aqua] Starosta, Wojciech Leciejewicz, Janusz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Li(C(5)H(4)N(3)O(2))(H(2)O)](n), is composed of centrosymmetric dinuclear units, in which the Li(I) ions are bridged by two carboxyl­ate O atoms donated by two ligands. The dinuclear unit is nearly planar [r.m.s. deviation = 0.0125 (2) Å]. The Li(I) ion is coordinated by an N,O-chelating ligand, a bridging carboxyl­ate O atom from another ligand and two bridging water O atoms in a distorted trigonal-bipyra­midal geometry. The water O atoms bridge the dinuclear units into a polymeric mol­ecular column along [010]. The columns are held together by O—H⋯O and N—H⋯N hydrogen bonds. An intra­molecular N—H⋯O inter­action also occurs. International Union of Crystallography 2010-06-05 /pmc/articles/PMC3006785/ /pubmed/21587683 http://dx.doi.org/10.1107/S1600536810020647 Text en © Starosta and Leciejewicz 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Starosta, Wojciech
Leciejewicz, Janusz
catena-Poly[[bis­(μ-3-amino­pyrazine-2-carboxyl­ato)-κ(3) N (1),O:O;κ(3) O:N (1),O)dilithium]-di-μ-aqua]
title catena-Poly[[bis­(μ-3-amino­pyrazine-2-carboxyl­ato)-κ(3) N (1),O:O;κ(3) O:N (1),O)dilithium]-di-μ-aqua]
title_full catena-Poly[[bis­(μ-3-amino­pyrazine-2-carboxyl­ato)-κ(3) N (1),O:O;κ(3) O:N (1),O)dilithium]-di-μ-aqua]
title_fullStr catena-Poly[[bis­(μ-3-amino­pyrazine-2-carboxyl­ato)-κ(3) N (1),O:O;κ(3) O:N (1),O)dilithium]-di-μ-aqua]
title_full_unstemmed catena-Poly[[bis­(μ-3-amino­pyrazine-2-carboxyl­ato)-κ(3) N (1),O:O;κ(3) O:N (1),O)dilithium]-di-μ-aqua]
title_short catena-Poly[[bis­(μ-3-amino­pyrazine-2-carboxyl­ato)-κ(3) N (1),O:O;κ(3) O:N (1),O)dilithium]-di-μ-aqua]
title_sort catena-poly[[bis­(μ-3-amino­pyrazine-2-carboxyl­ato)-κ(3) n (1),o:o;κ(3) o:n (1),o)dilithium]-di-μ-aqua]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006785/
https://www.ncbi.nlm.nih.gov/pubmed/21587683
http://dx.doi.org/10.1107/S1600536810020647
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