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catena-Poly[[bis(μ-3-aminopyrazine-2-carboxylato)-κ(3) N (1),O:O;κ(3) O:N (1),O)dilithium]-di-μ-aqua]
The title compound, [Li(C(5)H(4)N(3)O(2))(H(2)O)](n), is composed of centrosymmetric dinuclear units, in which the Li(I) ions are bridged by two carboxylate O atoms donated by two ligands. The dinuclear unit is nearly planar [r.m.s. deviation = 0.0125 (2) Å]. The Li(I) ion is coordinated by an N,O-...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006785/ https://www.ncbi.nlm.nih.gov/pubmed/21587683 http://dx.doi.org/10.1107/S1600536810020647 |
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author | Starosta, Wojciech Leciejewicz, Janusz |
author_facet | Starosta, Wojciech Leciejewicz, Janusz |
author_sort | Starosta, Wojciech |
collection | PubMed |
description | The title compound, [Li(C(5)H(4)N(3)O(2))(H(2)O)](n), is composed of centrosymmetric dinuclear units, in which the Li(I) ions are bridged by two carboxylate O atoms donated by two ligands. The dinuclear unit is nearly planar [r.m.s. deviation = 0.0125 (2) Å]. The Li(I) ion is coordinated by an N,O-chelating ligand, a bridging carboxylate O atom from another ligand and two bridging water O atoms in a distorted trigonal-bipyramidal geometry. The water O atoms bridge the dinuclear units into a polymeric molecular column along [010]. The columns are held together by O—H⋯O and N—H⋯N hydrogen bonds. An intramolecular N—H⋯O interaction also occurs. |
format | Text |
id | pubmed-3006785 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30067852010-12-30 catena-Poly[[bis(μ-3-aminopyrazine-2-carboxylato)-κ(3) N (1),O:O;κ(3) O:N (1),O)dilithium]-di-μ-aqua] Starosta, Wojciech Leciejewicz, Janusz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Li(C(5)H(4)N(3)O(2))(H(2)O)](n), is composed of centrosymmetric dinuclear units, in which the Li(I) ions are bridged by two carboxylate O atoms donated by two ligands. The dinuclear unit is nearly planar [r.m.s. deviation = 0.0125 (2) Å]. The Li(I) ion is coordinated by an N,O-chelating ligand, a bridging carboxylate O atom from another ligand and two bridging water O atoms in a distorted trigonal-bipyramidal geometry. The water O atoms bridge the dinuclear units into a polymeric molecular column along [010]. The columns are held together by O—H⋯O and N—H⋯N hydrogen bonds. An intramolecular N—H⋯O interaction also occurs. International Union of Crystallography 2010-06-05 /pmc/articles/PMC3006785/ /pubmed/21587683 http://dx.doi.org/10.1107/S1600536810020647 Text en © Starosta and Leciejewicz 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Starosta, Wojciech Leciejewicz, Janusz catena-Poly[[bis(μ-3-aminopyrazine-2-carboxylato)-κ(3) N (1),O:O;κ(3) O:N (1),O)dilithium]-di-μ-aqua] |
title |
catena-Poly[[bis(μ-3-aminopyrazine-2-carboxylato)-κ(3)
N
(1),O:O;κ(3)
O:N
(1),O)dilithium]-di-μ-aqua] |
title_full |
catena-Poly[[bis(μ-3-aminopyrazine-2-carboxylato)-κ(3)
N
(1),O:O;κ(3)
O:N
(1),O)dilithium]-di-μ-aqua] |
title_fullStr |
catena-Poly[[bis(μ-3-aminopyrazine-2-carboxylato)-κ(3)
N
(1),O:O;κ(3)
O:N
(1),O)dilithium]-di-μ-aqua] |
title_full_unstemmed |
catena-Poly[[bis(μ-3-aminopyrazine-2-carboxylato)-κ(3)
N
(1),O:O;κ(3)
O:N
(1),O)dilithium]-di-μ-aqua] |
title_short |
catena-Poly[[bis(μ-3-aminopyrazine-2-carboxylato)-κ(3)
N
(1),O:O;κ(3)
O:N
(1),O)dilithium]-di-μ-aqua] |
title_sort | catena-poly[[bis(μ-3-aminopyrazine-2-carboxylato)-κ(3)
n
(1),o:o;κ(3)
o:n
(1),o)dilithium]-di-μ-aqua] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006785/ https://www.ncbi.nlm.nih.gov/pubmed/21587683 http://dx.doi.org/10.1107/S1600536810020647 |
work_keys_str_mv | AT starostawojciech catenapolybism3aminopyrazine2carboxylatok3n1ook3on1odilithiumdimaqua AT leciejewiczjanusz catenapolybism3aminopyrazine2carboxylatok3n1ook3on1odilithiumdimaqua |