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(2E)-1-(2-Bromophenyl)-3-(3,4,5-trimethoxyphenyl)prop-2-en-1-one
In the chalcone title compound, C(18)H(17)BrO(4), the dihedral angle between the mean planes of the 2-bromo- and 3,4,5-trimethoxy-substituted benzene rings is 89.3 (1)°. The angles between the mean plane of the prop-2-en-1-one group and the 2-bromophenyl and 3,4,5-trimethoxyphenyl ring planes are...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006788/ https://www.ncbi.nlm.nih.gov/pubmed/21587901 http://dx.doi.org/10.1107/S160053681002235X |
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author | Jasinski, Jerry P. Butcher, Ray J. Veena, K. Narayana, B. Yathirajan, H. S. |
author_facet | Jasinski, Jerry P. Butcher, Ray J. Veena, K. Narayana, B. Yathirajan, H. S. |
author_sort | Jasinski, Jerry P. |
collection | PubMed |
description | In the chalcone title compound, C(18)H(17)BrO(4), the dihedral angle between the mean planes of the 2-bromo- and 3,4,5-trimethoxy-substituted benzene rings is 89.3 (1)°. The angles between the mean plane of the prop-2-en-1-one group and the 2-bromophenyl and 3,4,5-trimethoxyphenyl ring planes are 59.7 (1) and 40.5 (8)°, respectively. While no classical hydrogen bonds are present, three weak intermolecular C—H⋯O interactions and weak C—H⋯Br and C—H⋯Cg π-ring stacking interactions [C—H⋯Cg distance = 3.377 (2) Å] are observed, which contribute to the stability of crystal packing. |
format | Text |
id | pubmed-3006788 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30067882010-12-30 (2E)-1-(2-Bromophenyl)-3-(3,4,5-trimethoxyphenyl)prop-2-en-1-one Jasinski, Jerry P. Butcher, Ray J. Veena, K. Narayana, B. Yathirajan, H. S. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the chalcone title compound, C(18)H(17)BrO(4), the dihedral angle between the mean planes of the 2-bromo- and 3,4,5-trimethoxy-substituted benzene rings is 89.3 (1)°. The angles between the mean plane of the prop-2-en-1-one group and the 2-bromophenyl and 3,4,5-trimethoxyphenyl ring planes are 59.7 (1) and 40.5 (8)°, respectively. While no classical hydrogen bonds are present, three weak intermolecular C—H⋯O interactions and weak C—H⋯Br and C—H⋯Cg π-ring stacking interactions [C—H⋯Cg distance = 3.377 (2) Å] are observed, which contribute to the stability of crystal packing. International Union of Crystallography 2010-06-16 /pmc/articles/PMC3006788/ /pubmed/21587901 http://dx.doi.org/10.1107/S160053681002235X Text en © Jasinski et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Jasinski, Jerry P. Butcher, Ray J. Veena, K. Narayana, B. Yathirajan, H. S. (2E)-1-(2-Bromophenyl)-3-(3,4,5-trimethoxyphenyl)prop-2-en-1-one |
title | (2E)-1-(2-Bromophenyl)-3-(3,4,5-trimethoxyphenyl)prop-2-en-1-one |
title_full | (2E)-1-(2-Bromophenyl)-3-(3,4,5-trimethoxyphenyl)prop-2-en-1-one |
title_fullStr | (2E)-1-(2-Bromophenyl)-3-(3,4,5-trimethoxyphenyl)prop-2-en-1-one |
title_full_unstemmed | (2E)-1-(2-Bromophenyl)-3-(3,4,5-trimethoxyphenyl)prop-2-en-1-one |
title_short | (2E)-1-(2-Bromophenyl)-3-(3,4,5-trimethoxyphenyl)prop-2-en-1-one |
title_sort | (2e)-1-(2-bromophenyl)-3-(3,4,5-trimethoxyphenyl)prop-2-en-1-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006788/ https://www.ncbi.nlm.nih.gov/pubmed/21587901 http://dx.doi.org/10.1107/S160053681002235X |
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