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(E)-2,3-Dimethyl-N-(2-nitro­benzyl­idene)aniline

In the title compound, C(15)H(14)N(2)O(2), the 2,3-dimethyl­anilinic and benzaldehyde groups are planar, with r.m.s. deviations of 0.0101 and 0.0241 Å, respectively, and are oriented at a dihedral angle of 11.69 (3)°. The nitro group is inclined to the benzaldehyde group by 34.02 (9)°. The mol­ecule...

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Detalles Bibliográficos
Autores principales: Tahir, M. Nawaz, Tariq, Muhammad Ilyas, Ahmad, Shahbaz, Sarfraz, Muhammad, Ather, Abdul Qayyum
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006792/
https://www.ncbi.nlm.nih.gov/pubmed/21588024
http://dx.doi.org/10.1107/S1600536810024165
Descripción
Sumario:In the title compound, C(15)H(14)N(2)O(2), the 2,3-dimethyl­anilinic and benzaldehyde groups are planar, with r.m.s. deviations of 0.0101 and 0.0241 Å, respectively, and are oriented at a dihedral angle of 11.69 (3)°. The nitro group is inclined to the benzaldehyde group by 34.02 (9)°. The mol­ecule adopts an E configuration about the C=N bond. In the crystal, mol­ecules are linked via C—H⋯O inter­actions, giving rise to the formation of zigzag polymeric chains extending along [010]. They are also linked by C—H⋯π, and π–π inter­actions [centroid–centroid distance of 3.7185 (11) Å] involving symmetry-related aniline and benzene rings. The H atoms of the ortho-methyl group are disordered over two sites with a refined occupancy ratio of 0.69 (2):0.31 (2).