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16-[(E)-Benzylidene]-13-hydroxy-4-methyl-2-phenyl-4,14-diazapentacyclo-[12.3.1.0(1,5).0(5,13).0(7,12)]octadeca-7(12),8,10-triene-6,17-dione
In the title compound, C(30)H(26)N(2)O(3), the two pyrrolidine rings adopt twisted and envelope conformations, whereas the cyclopentane ring adopts an envelope conformation. The least-squares planes through the pyrrolidine rings form a dihedral angle of 41.72 (10)°. The molecular structure is stab...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006797/ https://www.ncbi.nlm.nih.gov/pubmed/21587787 http://dx.doi.org/10.1107/S1600536810020271 |
| Sumario: | In the title compound, C(30)H(26)N(2)O(3), the two pyrrolidine rings adopt twisted and envelope conformations, whereas the cyclopentane ring adopts an envelope conformation. The least-squares planes through the pyrrolidine rings form a dihedral angle of 41.72 (10)°. The molecular structure is stabilized by an intramolecular O—H⋯N hydrogen bond, which generates an S(5) ring motif. Centrosymmetrically related molecules are linked via two pairs of intermolecular C—H⋯O interactions, forming R (2) (2)(16) ring motifs. In the crystal packing, the molecules are linked into two-dimensional networks parallel to the ab plane via C—H⋯O interactions. |
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