16-[(E)-Benzyl­idene]-13-hy­droxy-4-methyl-2-phenyl-4,14-diaza­penta­cyclo-[12.3.1.0(1,5).0(5,13).0(7,12)]octa­deca-7(12),8,10-triene-6,17-dione

In the title compound, C(30)H(26)N(2)O(3), the two pyrrolidine rings adopt twisted and envelope conformations, whereas the cyclo­pentane ring adopts an envelope conformation. The least-squares planes through the pyrrolidine rings form a dihedral angle of 41.72 (10)°. The mol­ecular structure is stab...

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Autores principales: Kumar, Raju Suresh, Osman, Hasnah, Ali, Mohamed Ashraf, Quah, Ching Kheng, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006797/
https://www.ncbi.nlm.nih.gov/pubmed/21587787
http://dx.doi.org/10.1107/S1600536810020271
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author Kumar, Raju Suresh
Osman, Hasnah
Ali, Mohamed Ashraf
Quah, Ching Kheng
Fun, Hoong-Kun
author_facet Kumar, Raju Suresh
Osman, Hasnah
Ali, Mohamed Ashraf
Quah, Ching Kheng
Fun, Hoong-Kun
author_sort Kumar, Raju Suresh
collection PubMed
description In the title compound, C(30)H(26)N(2)O(3), the two pyrrolidine rings adopt twisted and envelope conformations, whereas the cyclo­pentane ring adopts an envelope conformation. The least-squares planes through the pyrrolidine rings form a dihedral angle of 41.72 (10)°. The mol­ecular structure is stabilized by an intra­molecular O—H⋯N hydrogen bond, which generates an S(5) ring motif. Centrosymmetrically related mol­ecules are linked via two pairs of inter­molecular C—H⋯O inter­actions, forming R (2) (2)(16) ring motifs. In the crystal packing, the mol­ecules are linked into two-dimensional networks parallel to the ab plane via C—H⋯O inter­actions.
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spelling pubmed-30067972010-12-30 16-[(E)-Benzyl­idene]-13-hy­droxy-4-methyl-2-phenyl-4,14-diaza­penta­cyclo-[12.3.1.0(1,5).0(5,13).0(7,12)]octa­deca-7(12),8,10-triene-6,17-dione Kumar, Raju Suresh Osman, Hasnah Ali, Mohamed Ashraf Quah, Ching Kheng Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(30)H(26)N(2)O(3), the two pyrrolidine rings adopt twisted and envelope conformations, whereas the cyclo­pentane ring adopts an envelope conformation. The least-squares planes through the pyrrolidine rings form a dihedral angle of 41.72 (10)°. The mol­ecular structure is stabilized by an intra­molecular O—H⋯N hydrogen bond, which generates an S(5) ring motif. Centrosymmetrically related mol­ecules are linked via two pairs of inter­molecular C—H⋯O inter­actions, forming R (2) (2)(16) ring motifs. In the crystal packing, the mol­ecules are linked into two-dimensional networks parallel to the ab plane via C—H⋯O inter­actions. International Union of Crystallography 2010-06-05 /pmc/articles/PMC3006797/ /pubmed/21587787 http://dx.doi.org/10.1107/S1600536810020271 Text en © Kumar et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kumar, Raju Suresh
Osman, Hasnah
Ali, Mohamed Ashraf
Quah, Ching Kheng
Fun, Hoong-Kun
16-[(E)-Benzyl­idene]-13-hy­droxy-4-methyl-2-phenyl-4,14-diaza­penta­cyclo-[12.3.1.0(1,5).0(5,13).0(7,12)]octa­deca-7(12),8,10-triene-6,17-dione
title 16-[(E)-Benzyl­idene]-13-hy­droxy-4-methyl-2-phenyl-4,14-diaza­penta­cyclo-[12.3.1.0(1,5).0(5,13).0(7,12)]octa­deca-7(12),8,10-triene-6,17-dione
title_full 16-[(E)-Benzyl­idene]-13-hy­droxy-4-methyl-2-phenyl-4,14-diaza­penta­cyclo-[12.3.1.0(1,5).0(5,13).0(7,12)]octa­deca-7(12),8,10-triene-6,17-dione
title_fullStr 16-[(E)-Benzyl­idene]-13-hy­droxy-4-methyl-2-phenyl-4,14-diaza­penta­cyclo-[12.3.1.0(1,5).0(5,13).0(7,12)]octa­deca-7(12),8,10-triene-6,17-dione
title_full_unstemmed 16-[(E)-Benzyl­idene]-13-hy­droxy-4-methyl-2-phenyl-4,14-diaza­penta­cyclo-[12.3.1.0(1,5).0(5,13).0(7,12)]octa­deca-7(12),8,10-triene-6,17-dione
title_short 16-[(E)-Benzyl­idene]-13-hy­droxy-4-methyl-2-phenyl-4,14-diaza­penta­cyclo-[12.3.1.0(1,5).0(5,13).0(7,12)]octa­deca-7(12),8,10-triene-6,17-dione
title_sort 16-[(e)-benzyl­idene]-13-hy­droxy-4-methyl-2-phenyl-4,14-diaza­penta­cyclo-[12.3.1.0(1,5).0(5,13).0(7,12)]octa­deca-7(12),8,10-triene-6,17-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006797/
https://www.ncbi.nlm.nih.gov/pubmed/21587787
http://dx.doi.org/10.1107/S1600536810020271
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