6-Nitro­benzimidazolium dihydrogen phosphate 6-nitro­benzimidazole solvate dihydrate

In the crystal structure of the title compound, C(7)H(6)N(3)O(2) (+)·H(2)PO(4) (−)·C(7)H(5)N(3)O(2)·2H(2)O, the components are connected through O—H⋯O, N—H⋯O and O—H⋯N hydrogen-bonding inter­actions, forming a sheet-like structure parallel to (101). Adjacent sheets are further linked together by str...

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Autores principales: Shao, Zhi-Dong, Jiang, Xiao, Lan, Shao-Min, Di, Wen-Jing, Liang, Yun-Xiao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006800/
https://www.ncbi.nlm.nih.gov/pubmed/21587973
http://dx.doi.org/10.1107/S1600536810023603
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author Shao, Zhi-Dong
Jiang, Xiao
Lan, Shao-Min
Di, Wen-Jing
Liang, Yun-Xiao
author_facet Shao, Zhi-Dong
Jiang, Xiao
Lan, Shao-Min
Di, Wen-Jing
Liang, Yun-Xiao
author_sort Shao, Zhi-Dong
collection PubMed
description In the crystal structure of the title compound, C(7)H(6)N(3)O(2) (+)·H(2)PO(4) (−)·C(7)H(5)N(3)O(2)·2H(2)O, the components are connected through O—H⋯O, N—H⋯O and O—H⋯N hydrogen-bonding inter­actions, forming a sheet-like structure parallel to (101). Adjacent sheets are further linked together by strong O—H⋯O hydrogen-bonds involving the dihydrogenphosphate groups. π–π stacking inter­actions between neighbouring aromatic constituents [centroid–centroid distance 3.653 (3) Å] help to consolidate the crystal packing.
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spelling pubmed-30068002010-12-30 6-Nitro­benzimidazolium dihydrogen phosphate 6-nitro­benzimidazole solvate dihydrate Shao, Zhi-Dong Jiang, Xiao Lan, Shao-Min Di, Wen-Jing Liang, Yun-Xiao Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(7)H(6)N(3)O(2) (+)·H(2)PO(4) (−)·C(7)H(5)N(3)O(2)·2H(2)O, the components are connected through O—H⋯O, N—H⋯O and O—H⋯N hydrogen-bonding inter­actions, forming a sheet-like structure parallel to (101). Adjacent sheets are further linked together by strong O—H⋯O hydrogen-bonds involving the dihydrogenphosphate groups. π–π stacking inter­actions between neighbouring aromatic constituents [centroid–centroid distance 3.653 (3) Å] help to consolidate the crystal packing. International Union of Crystallography 2010-06-23 /pmc/articles/PMC3006800/ /pubmed/21587973 http://dx.doi.org/10.1107/S1600536810023603 Text en © Shao et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shao, Zhi-Dong
Jiang, Xiao
Lan, Shao-Min
Di, Wen-Jing
Liang, Yun-Xiao
6-Nitro­benzimidazolium dihydrogen phosphate 6-nitro­benzimidazole solvate dihydrate
title 6-Nitro­benzimidazolium dihydrogen phosphate 6-nitro­benzimidazole solvate dihydrate
title_full 6-Nitro­benzimidazolium dihydrogen phosphate 6-nitro­benzimidazole solvate dihydrate
title_fullStr 6-Nitro­benzimidazolium dihydrogen phosphate 6-nitro­benzimidazole solvate dihydrate
title_full_unstemmed 6-Nitro­benzimidazolium dihydrogen phosphate 6-nitro­benzimidazole solvate dihydrate
title_short 6-Nitro­benzimidazolium dihydrogen phosphate 6-nitro­benzimidazole solvate dihydrate
title_sort 6-nitro­benzimidazolium dihydrogen phosphate 6-nitro­benzimidazole solvate dihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006800/
https://www.ncbi.nlm.nih.gov/pubmed/21587973
http://dx.doi.org/10.1107/S1600536810023603
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