Hexa­kis­(dimethyl sulfoxide-κO)thallium(III) trinitrate

The title compound, [Tl(C(2)H(6)OS)(6)](NO(3))(3), consists of six dimethyl sulfoxide (DMSO) mol­ecules coordinated to a Tl(III) atom, which lies on a [Image: see text] axis, and three nitrate anions (3. symmetry) to neutralize the charge. The coordination polyhedron around the Tl(III) atom is octa­...

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Detalles Bibliográficos
Autores principales: Ghadermazi, Mohammad, Manteghi, Faranak
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3006801/
https://www.ncbi.nlm.nih.gov/pubmed/21587730
http://dx.doi.org/10.1107/S1600536810022646
Descripción
Sumario:The title compound, [Tl(C(2)H(6)OS)(6)](NO(3))(3), consists of six dimethyl sulfoxide (DMSO) mol­ecules coordinated to a Tl(III) atom, which lies on a [Image: see text] axis, and three nitrate anions (3. symmetry) to neutralize the charge. The coordination polyhedron around the Tl(III) atom is octa­hedral, defined by six O atoms of the DMSO mol­ecules. In the crystal structure, C—H⋯O hydrogen bonds are observed. One of the nitrate groups exhibits half-occupation.

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